Journal
ORGANIC LETTERS
Volume 11, Issue 20, Pages 4536-4539Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901776n
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Funding
- National Natural Science Foundation of China [20802085, 20625308]
- Chinese Academy of Sciences
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A new and efficient route for synthesis of enantiomerically pure biisoindoline and its isomer based on the diaza-Cope rearrangement reaction with chiral 1,2-bis(2-hydroxylphenyl)-1,2-diaminoethane as starting material has been developed. The newly prepared biisoindoline was employed as a chiral ligand in the NI(II)-catalyzed enantioselective Michael addition of malonates to conjugated nitroalkenes, and good to excellent enantioselectivities were obtained.
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