Journal
ORGANIC LETTERS
Volume 11, Issue 11, Pages 2309-2312Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900643r
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Funding
- New Century Excellent Talents in University [NCET-06-0711]
- Scientific Research Fund of Hunan Provincial Education Department [08B053, 08A037]
- Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China) [KL-CBTCMR2008-11]
- Hunan Normal University [080605]
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A novel and selective protocol for the synthesis of 1-allyl-2-ethynylbenzenes has been developed by palladium-catalyzed decarboxylative coupling of allylic alkynoates with arynes. This new route allows for both sp-sp(2) and sp(2)-sp(3) couplings of allylic alkynoates with arynes in one pot involving a decarboxylation process.
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