Journal
ORGANIC LETTERS
Volume 11, Issue 19, Pages 4470-4473Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901866y
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- Grants-in-Aid for Scientific Research [20249002, 21790013] Funding Source: KAKEN
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Highly enantioselective rhodium-catalyzed addition of arylboroxines to N-phosphinoylaldi mines was realized by the steric tuning of a cliphenylphosphorus moiety to a di(o-tolyl) phosphorus moiety of a chiral amidomonophosphane. The presence of MS 4 A in a 5:1 solvent mixture of dioxane-propanol was essential to afford the corresponding diarylmethylamines in high yield.
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