Journal
ORGANIC LETTERS
Volume 11, Issue 20, Pages 4632-4635Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901912j
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Japan Private School Promotion Foundation
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Intermolecular hydroxyalkylation of alpha,beta-unsaturated imines Involving Et3B-mediated regioselective alkyl radical addition and subsequent hydroxylation with molecular oxygen has been developed, In which N-borylenamine generated by trapping of the enaminyl radical with Et3B was a key intermediate in the proposed aerobic hydroxylation mechanism.
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