Journal
ORGANIC LETTERS
Volume 11, Issue 1, Pages 117-120Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802465k
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Funding
- National Natural Science Foundation of China [20429201, 20732005]
- State Basic and Research Development Program [2006CB806105]
- Chinese Academy of Sciences
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An efficient and highly regioselective route to synthesize polysubstituted 1,3,4-alkatrien-2-yl cyclopropane derivatives via Pd(0)-catalyzed highly regioselective coupling cyclization of (2,3-butadienyl)malonate or bis(phenylsulfonyl)methane with propargylic carbonates was reported. The reaction proceeded smoothly under neutral conditions to afford the products in 73-96% yields. The products may be efficiently converted to cyclopentenone derivatives via a catalytic Pauson-Khand reaction under ambient conditions.
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