Journal
ORGANIC LETTERS
Volume 11, Issue 16, Pages 3594-3597Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901313z
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- Department of Chemistry at Temple University
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Two classes of gem-dimethyl 4-n-pentenyl glycosides (i.e., C2-series and C3-series) have been prepared and studied in both the glycosylation and hydrolysis manifolds utilizing NBS as the sole stoichiometric activator. These novel glycosylating agents, which are analogues of Fraser-Reid's 4-n-penterryl glycosyl donors, show increased reactivity in side-by-side studies by virtue of the gem-dimethyl effect.
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