Journal
ORGANIC LETTERS
Volume 11, Issue 8, Pages 1729-1732Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900137r
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Funding
- CREST from the Japan Science and Technology Agency [19205020]
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Grants-in-Aid for Scientific Research [19205020] Funding Source: KAKEN
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Novel phenylazomethine dendrimers with a disulfide core (SS-DPA G1-4) were synthesized in nearly quantitative yields. Although the disulfide core is shielded by the rigid dendron shell, direct formation of the self-assembled monolayers of metal-assembling dendron thiolate was observed by XPS and electrochemical reduction of the self-assembled monolayer substrates. The dendrimers showed a similar metal-assembling manner with other derivatives. The metal assembly to the self-assembled monolayers of metal-assembling dendron thiolate was also confirmed.
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