Journal
ORGANIC LETTERS
Volume 10, Issue 14, Pages 3085-3088Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8010826
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1,2,3-Benzotriazin-4(3(H)-ones reacted with internal and terminal alkynes in the presence of a nickel(0)/phosphine catalyst to give a wide range of substituted 1(2H)-isoquinolones in high yield. The reaction proceeded through denitrogenative activation of the triazinone moiety and the following insertion of alkynes.
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