Journal
ORGANIC LETTERS
Volume 10, Issue 12, Pages 2485-2488Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800765s
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In the presence of carbon tetrabromide, a variety of dithiocarbamates, xanthates, dithioesters, and thioethers were prepared in one pot by reacting the corresponding dithioic acids or thiols with active methylene compounds/indole derivatives under mild conditions. The formation of a sulfenyl bromide intermediate is proposed as the key step, which initiates the C-S bond formation.
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