Journal
ORGANIC LETTERS
Volume 10, Issue 8, Pages 1665-1668Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800429j
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Funding
- NIGMS NIH HHS [R01 GM072572, GM 72572, R01 GM072572-01] Funding Source: Medline
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Irradiation of 2-(3-alkenyl)allenylphenyl azides in the presence of excess Cul furnished functionalized 2,3-cyclopentenylindoles in good yield with only trace amounts of competitive C-N-bonded regioisomeric products. These results represent a significant departure from the modestto-nonexistent regioselectivity that attended thermal cyclization of these allenyl azide substrates.
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