Journal
ORGANIC LETTERS
Volume 10, Issue 19, Pages 4227-4229Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801604z
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Funding
- the Australian Research Council
- the Commonwealth Scientific Industrial Research Organisation
- the Victorian Endowment for Science Knowledge and Innovation
- the Engineering and Physical Sciences Research Council
- UK (Swansea National MS Service)
- The University of Melbourne
- Merck, Sharp and Dohme
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Starting from commercially available (S)-glycidol, and via a common intermediate, the total synthesis of (-)-histrionicotoxin 285A and (-)perhydrohistrionicotoxin has been achieved. Key to this synthesis was the efficient construction of a six-membered, chiral, cyclic nitrone.
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