Journal
ORGANIC LETTERS
Volume 10, Issue 12, Pages 2417-2420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800698t
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Halohydrin dehalogenase from Agrobacterium radiobacter catalyzed the enantioselective ring opening of terminal epoxides with cyanate as a nucleophile, yielding 5-substituted oxazolidinones in high yields and with high enantiopurity (69-98% ee). This is the first example of the biocatalytic conversion of a range of epoxides to the corresponding oxazolidinones.
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