Journal
ORGANIC LETTERS
Volume 10, Issue 22, Pages 5247-5250Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802328n
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Funding
- Damon Runyon Cancer Research Foundation [DRG: 1961-07]
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A rapid and scalable synthesis of the carbocyclic core of the potent antiangiogenic natural products, the cortistatins, is presented starting from readily available (+)-estrone. Key steps include a regio- and stereoselective benzylic cyanation and a Demjanov rearrangement.
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