Journal
ORGANIC LETTERS
Volume 10, Issue 7, Pages 1453-1456Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800225t
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The issue of the added value of NHCs in asymmetric catalysis with respect to trusted chiral P-ligands was addressed: considering a prototypical asymmetric allylic alkylation reaction as a model, the association of a priori inhibiting and achiral NHCs with modular P-ligand resulted in enhancement of er up to 508% and increased rates.
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