Journal
ORGANIC LETTERS
Volume 10, Issue 2, Pages 221-223Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702595d
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- NIGMS NIH HHS [GM 34442] Funding Source: Medline
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A new route to C-2-symmetric diamines via an asymmetric reductive dimerization of 1-acylpyridinium salts and their benzo derivatives is described. This method is practical as the starting heterocycles and chiral auxiliaries are readily available. The titanium reducing agent is inexpensive and easy to prepare. Several novel enantiopure C2-symmetric diamine derivatives were synthesized using this method.
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