4.6 Article

Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 14, Pages 2172-2175

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00066h

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Funding

  1. Council of Scientific and Industrial Research (CSIR) [CSC-0123]

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A direct transformation of N-aryl formamides to the corresponding carbamates via the formation of isocyanate intermediates is achieved in good yields using hypervalent iodine as an oxidant.

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