4.6 Article

Gold-catalyzed tandem Diels-Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 24, Pages 4104-4111

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00321g

Keywords

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Funding

  1. NNSFC [21172077, 21372086]
  2. National Basic Research Program of China (973) [2011CB808600]
  3. Changjiang Scholars and Innovation Team Project of Ministry of Education
  4. Fundamental Research Funds for the Central Universities
  5. SRF for ROCS
  6. State Education Ministry
  7. Guangdong NSF [10351064101000000]
  8. [NCET-10-0403]

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An efficient gold-catalyzed method to generate the highly reactive cyclic o-QDM species from the enynal/enynone and alkene is reported. This method allows rapid access to a variety of structurally unique propeller-like products through tandem Diels-Alder reactions.

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