4.6 Article

Gorlos-Phos for palladium-catalyzed borylation of aryl chlorides

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 22, Pages 3604-3610

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00293h

Keywords

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Funding

  1. National Natural Science Foundation of China [21172192]
  2. National Basic Research Program of China [2011CB808700]

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Using a readily available form of the mono-phosphine ligand, Gorlos-Phos center dot HBF4, Pd-catalyzed borylation of aryl chlorides afforded aryl boronates in high yields. A variety of functional groups are well compatible with this palladium catalyzed borylation reaction.

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