Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 21, Pages 3558-3567Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40379c
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On deprotonation, 1-arylindazolium salts form 1-arylindazol-3-ylidenes which rearrange spontaneously via ring cleavage, ring closure and subsequent proton transfer to substituted 9-aminoacridines. By contrast, the N-heterocyclic carbene of 2-phenylindazolium cannot rearrange similarly and was trapped by sulfur.
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