Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 11, Issue 12, Pages 2000-2004Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob27344f
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Funding
- DFG [1166]
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Enzymes create chiral microenvironments that may simultaneously generate several stereogenic centers in the same catalytic cycle, broadening the possibilities of biocatalysis. Benzaldehyde lyase (BAL) affords highly diastereoselective alpha-hydroxy-ketones by simultaneously performing ligation and kinetic resolution of a racemic aldehyde. Thus, to the well-known enantioselective BAL-carboligation of aldehydes (C-C bond formation), another property, namely diastereoselectivity, is added in this paper for the first time.
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