Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 7, Pages 1396-1405Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06671d
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Funding
- Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
- National Basic Research Program of China [(973)-2010CB833302]
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [21072206, 20472096, 20902019, 20872162, 20672127, 20821002, 20732008, 20702059]
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An efficient asymmetric substitution process of O-Boc-protected Morita-Baylis-Hillman adducts with various pyrrole and indole derivatives has been developed in the presence of (DHQD)(2)PYR in THF, affording the corresponding products in good to high yields (up to 99% yield) and moderate to high ee values (up to 92 and 96% ee) under mild conditions.
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