Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 29, Pages 5636-5642Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25540e
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- University of Johannesburg
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A temperature-controlled mechanism switch between the Al(OTf)(3)-catalysed direct addition of alcohols or the Ferrier rearrangement reactions in some glycals is presented. The scope and limitations are investigated as are the influence of the stereochemistry and nature of the protecting groups on the glycal substrate.
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