4.6 Article

A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 14, Pages 2753-2759

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob06949k

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Funding

  1. Indian Institute of Science, CSIR, New-Delhi [01(2415)/10/EMR-II]
  2. RL Fine Chem

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A novel non-metal catalyzed oxidation of organic azides to nitriles under solvent-free conditions is presented employing catalytic amounts of KI, and DABCO in aq. TBHP at room temperature. This nonmetal catalyzed oxidation of azides provides good selectivity as double and triple bonds were not oxidized under the present reaction conditions.

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