Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 15, Pages 2950-2954Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob07192d
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Funding
- National Sciences Foundation of China [21172217]
- National Basic Research Program of China (973 Program) [2010CB833300]
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By employing a chiral bifunctional thiourea-tertiary amine as catalyst, enantioselective Michael addition of a kojic acid derivative to nitro olefins was realised. The reactions afforded the products with good yields (up to 99%) in good enantioselectivities (up to 97% ee). In addition, the absolute configuration of one product was determined.
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