Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 10, Issue 18, Pages 3613-3616Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25492a
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Funding
- Natural Sciences and Engineering Research Council of Canada
- Canada Foundation for Innovation
- Saskatchewan Government
- University of Saskatchewan
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Although isocyanides are not rare amongst terrestrial microbes and marine organisms, despite tens of thousands of natural products isolated from plants, isocyanides are still missing. Isocyalexin A is the first isocyanide of plant origin. Isocyalexin A was isolated from UV-irradiated rutabaga roots and shown to be a new cruciferous phytoalexin. Its chemical structure was proven by analysis of NMR data and chemical synthesis.
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