Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 7, Pages 2198-2208Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00754d
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- Australian Postgraduate Award
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The total synthesis of the C-19 lipid diols 5 and 6, the enantiomers of the anthelmintic marine natural products 1 and 3, is described. Key steps in the divergent syntheses include a syn selective epoxidation of a homoallylic alcohol, a one-pot alkoxypalladation-carbonylation-lactonisation reaction sequence and a DMEAD promoted Mitsunobu inversion.
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