Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 9, Issue 10, Pages 3714-3725Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05069a
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Funding
- National Natural Science Foundation of China [20802048]
- Cultivation Foundation (B) for Young Faculty of Tianjin University [TJU-YFF-08B68]
- China Postdoctoral Science Foundation [200904507610]
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A variety of functionalized N-amino-3-nitrile-indole derivatives are obtained via an intramolecular hetero-cyclization of 2-aryl-3-substituted hydrazono-alkylnitriles using FeBr3 as a single electron oxidant. This approach allows the N-moiety on the side-chain to be annulated to the benzene ring during the final synthetic step via direct oxidative aromatic C-N bond formation.
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