4.6 Article

Size-dependent behaviors of femtosecond laser-prototyped polymer micronanowires

Journal

OPTICS LETTERS
Volume 34, Issue 5, Pages 566-568

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OL.34.000566

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Funding

  1. National Science Foundation of China (NSFC) [60525412, 60677018]
  2. Japan Society for the Promotion of Science, Japan [17201033]

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A remarkable recent progress in two-photon photopolymerization is the achievement of fabrication resolution around tens of nanometers, establishing a femtosecond laser as a nanofabrication tool. However, how the superresolution has been made possible is still under arguement. We propose a concept of polymer network permeability to solvents, meaning a structure-loosened nanopolymer state that allows free penetration of small molecules to interpret the mechanism. Experimentally, we found proof showing existence of the state, including an unusually large volume shrinkage rate (>60%), shape-memory effect, a giant softness of nanospring, and the mechanical stability of rinsed two-photon written polymer nanowires. (C) 2009 Optical Society of America

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