4.5 Article

Laser ablation fast pulse discharge plasma spectroscopy analysis of Pb, Mg and Sn in soil

Journal

OPTICS COMMUNICATIONS
Volume 285, Issue 1, Pages 54-58

Publisher

ELSEVIER
DOI: 10.1016/j.optcom.2011.08.074

Keywords

LIBS; Laser ablation; Fast pulse discharge plasma; Soil analysis

Categories

Funding

  1. National Natural Science Foundation of China [61178034]
  2. Universities in Zhejiang Province, China [ZD2009006]
  3. Natural Science Foundation of Zhejiang Province, China [Y1100268]
  4. Zhejiang Normal University, Jinhua, Zhejiang Province, China

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Laser ablation fast pulse discharge plasma spectroscopy (LA-FPDPS) technique is a recently developed atomic emission analytical technique that is analogous to dual pulse laser induced breakdown spectroscopy (DP-LIBS). LA-FPDPS, however, uses a periodical oscillating discharge plasma generation method on samples instead of the second laser beam in DP-LIBS. Here we describe the electric characteristics and its application to the analysis of Pb, Mg and Sn in soil. Due to the fast discharge process, the peak power deposition rate is up to 1.5 MW, although the discharge energy is relatively small. The main energy deposition process only last for similar to 4 mu s. From the measured spectra, calibration curves for Pb, Mg and Sn in soil were derived and the limits of detection were 1.5 mu g/g, 34 wig and 0.16 mu g/g respectively. (C) 2011 Elsevier B.V. All rights reserved.

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