Journal
TETRAHEDRON LETTERS
Volume 56, Issue 30, Pages 4413-4429Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.05.078
Keywords
Indole; Arylation; Dearomatization; Indoline; Natural products
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Funding
- Fondation pour le developpement de la chimie des substances naturelles et ses applications
- sous l'egide de l'Academie des Sciences
- ANR [ANR-12-JS07-0002]
- Ecole Doctorale Chimie de Paris-Sud [ED 470]
- Universite Paris Sud
- CNRS
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The introduction of aryl motifs at the C3-position of indole nuclei via dearomatization reactions has been the subject of intensive efforts in the last years and has culminated in several total syntheses of natural products. We provide in this digest Letter an overview of these recent advances including ours and we will highlight the fact that indoles could indeed act as nucleophiles but also as electrophiles and could be involved in radical reactions. (C) 2015 Elsevier Ltd. All rights reserved.
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