Journal
TETRAHEDRON LETTERS
Volume 56, Issue 1, Pages 192-194Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.11.072
Keywords
Asymmetric transfer hydrogenation; alpha-Hydroxy esters; Azides; Ru-TsDPEN catalyst; Lactates
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Funding
- Ningxia Natural Science Foundation [NZ13046]
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The asymmetric transfer hydrogenation of alpha-azido acrylates has been explored, a range of alpha-hydroxy esters are produced with good enantioselectivities (80-90% ee). The reaction was conducted in the wet HCO2H/NEt3 with Ru-TsDPEN A. (C) 2014 Elsevier Ltd. All rights reserved.
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