4.4 Article

Asymmetric synthesis of optically active spiroacetals from alkynyl glycols catalyzed by gold complex/Bronsted acid binary system

Journal

TETRAHEDRON LETTERS
Volume 56, Issue 21, Pages 2651-2655

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.03.007

Keywords

Spiroacetals; Binary system; Asymmetric synthesis

Funding

  1. NSFC [21062021]

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An asymmetric catalytic synthesis of optically active spiroacetals from alkynyl glycols has been well established by using gold complex/Bronsted acid binary system in relay manner. A wide range of spiroacetals were obtained in good yields and with high enantioselectivities. (C) 2015 Published by Elsevier Ltd.

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