Journal
TETRAHEDRON LETTERS
Volume 56, Issue 48, Pages 6726-6729Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.10.056
Keywords
Solid phase synthesis; Peptoid; Reductive amination; Foldamer
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Funding
- Japan Society for the Promotion of Science [15H03836]
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [15H00809]
- Takeda Life Science Foundation
- Grants-in-Aid for Scientific Research [15H03836, 15H00809] Funding Source: KAKEN
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Herein, we describe a new methodology for the solid phase submonomer synthesis (SPSS) of arylopeptoids using a reductive amination reaction as the key step instead of a nucleophilic substitution reaction, which is generally used in conventional SPSS of peptoids. The new SPSS enables easy access to arylopeptoid oligomers in which phenyl side groups are directly attached to the aromatic main chain. (C) 2015 Elsevier Ltd. All rights reserved.
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