Journal
TETRAHEDRON LETTERS
Volume 56, Issue 17, Pages 2203-2206Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.03.032
Keywords
5-Substituted 1H-tetrazoles; Cyanuric chloride; [2+3] cycloaddition; Nitriles; Sodium azide
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Funding
- Council of Scientific and Industrial Research, New Delhi, India [02(0025)/11/EMR-II]
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A wide variety of nitriles react with sodium azide in the presence of a catalytic amount of cyanuric chloride or 2,4,6-trichloro-1,3,5-triazine (TCT) under mild reaction conditions to give the corresponding 5-substituted-1H-tetrazoles in good to excellent yields. Here, we used TCT as a source of hydrochloric acid to catalyze this cycloaddition reaction. (C) 2015 Elsevier Ltd. All rights reserved.
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