Journal
TETRAHEDRON LETTERS
Volume 56, Issue 31, Pages 4623-4626Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.06.017
Keywords
N-arylation; Amidine; N,N-Disubstituted amidine; o-Silylaryl triflate; Metal-free
Categories
Funding
- Shaanxi University of Science Technology
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A metal-free method for the N-arylation of amidines and N,N-disubstituted amidines using o-silylaryl triflate under very mild reaction conditions is developed. The reactions are compatible with a variety of functional groups. Imines can also be N-arylated by this method. Preparation of substituted phenanthridines via a Pd catalyzed intramolecular cyclization of the iodine containing N-arylation product is demonstrated. (C) 2015 Elsevier Ltd. All rights reserved.
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