Journal
TETRAHEDRON
Volume 71, Issue 8, Pages 1215-1226Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.01.007
Keywords
Indium; N-Heterocycles; Reduction-triggered cyclization; One-pot quinoxaline synthesis
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Funding
- Kwangwoon University
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The one-pot reduction-cyclization of 2-nitroanilines and 1,2-diketones to give quinoxalines was investigated. Using indium and an appropriate acid such as acetic acid or indium(III) chloride, various quinoxaline derivatives including 2,3-dialkylquinoxalines, 2,3-diphenylquinoxalines, 2,3-di-2-thiophenylquinoxalines, 2,3-di(pyridin-2-yl)quinoxalines, and dibenzo[a,c]phenazines were synthesized in moderate to excellent yield. (C) 2015 Elsevier Ltd. All rights reserved.
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