Journal
TETRAHEDRON
Volume 71, Issue 5, Pages 869-874Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.12.041
Keywords
Enynes; Gold; Cyclization; Aromatization; Naphthols
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Funding
- Japan Society for the Promotion of Science, Japan [25410054]
- Sumitomo Foundation [130325]
- Grants-in-Aid for Scientific Research [25410054] Funding Source: KAKEN
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The gold(I)-catalyzed oxidative cyclization of 2-alkenylphenyl alkynyl ketones employing organic oxides as oxidants has been developed. This reaction involves aromatization to furnish 2-acyl-1-naphthols. Also, 10-acyl-9-phenanthrenols are analogously produced from the reaction of allcynyl 2-biphenyl ketones. (C) 2014 Elsevier Ltd. All rights reserved.
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