Journal
TETRAHEDRON
Volume 71, Issue 25, Pages 4282-4295Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.04.078
Keywords
Azocarboxylic esters; 1,2,4-Triazoles; Glycine imines; Cycloaddition; Azo compounds
Categories
Funding
- Deutsche Forschungs-gemeinschaft (DFG) [HE5413/3-1, GRK1910/B3]
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Phenylazocarboxylic tert-butyl esters have recently been shown to be highly versatile building blocks due to their ability to undergo nucleophilic aromatic substitutions under mild conditions, particularly well with [F-18]fluoride, and to act as precursors for aryl radicals. In this article, we now report first examples for cycloaddition reactions to phenylazocarboxylates. In a one-pot reaction with readily accessible glycine imines, a variety of highly substituted 1,2,4-triazoles could be obtained. (C) 2015 Elsevier Ltd. All rights reserved.
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