Article
Green & Sustainable Science & Technology
Nadia Shahzad, Lutfullah, Tahira Perveen, Diego Pugliese, Sirajul Haq, Nusrat Fatima, Syed Muhammad Salman, Alberto Tagliaferro, Muhammad Imran Shahzad
Summary: Efficiency, stability, and cost-effectiveness are the prime challenges in research of materials for solar cells. This study explores carbon nanotubes as alternative counter electrode materials for dye-sensitized solar cells (DSSCs) and discusses various classes of carbon nanotube-based counter electrode materials comprehensively. The properties associated with these materials are analyzed and compared. Additionally, this study includes a brief overview of materials for other components of DSSCs.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2022)
Article
Electrochemistry
Mahin Mirzaei, Mohammad Bagher Gholivand
Summary: In this study, a core-shell structured Ni0.85Se@MoS2@MWCNTs composite material was prepared to replace expensive platinum as the counter electrode in dye-sensitized solar cells. The composite material exhibited excellent electrocatalytic performance, electrical conductivity, and electrochemical stability, leading to a higher power conversion efficiency compared to the cell with platinum counter electrode. This research provides a cost-effective strategy for developing highly effective and robust non-precious-metal counter electrodes for next-generation energy storage and conversion devices.
ELECTROCHIMICA ACTA
(2022)
Article
Energy & Fuels
Aycan Atli, Abdullah Yildiz
Summary: An opaque platinum film as a counter electrode in dye-sensitized solar cells demonstrates enhanced reflectivity, smaller resistance, and excellent adhesion properties. As a result, the DSSC with the opaque platinum film achieves a higher electrical power conversion efficiency compared to the transparent platinum film under the same conditions.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Inorganic & Nuclear
Arimakula Chamatam Kasi Reddy, Maddala Gurulakshmi, Parnapalli Muni Mounika, Ambapuram Meenakshamma, Katta Venkateswarlu, Yorva Pedda Venkata Subbaiah, Mitty Raghavender
Summary: Counter electrodes (CEs) for dye-sensitized solar cells (DSSC) were fabricated using poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate (PEDOT:PSS) and platinum (Pt) solution, with high transparency and adhesion on an FTO glass substrate, through the Marker pen lithography coating method. The morphology and roughness of the PEDOT:PSS-MPL and Pt-MPL CEs were analyzed using scanning electron microscopy (SEM) and atomic force microscopy (AFM), while the electrochemical properties were evaluated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The device performance was assessed through current density-voltage (J-V) measurements, with the Pt-MPL and PEDOT:PSS-MPL CEs achieving power conversion efficiencies (PCE) of 4.25% and 3.00%, respectively, compared to dip coated PEDOT:PSS-DC and Pt-DC CEs.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Mahin Mirzaei, Mohammad Bagher Gholivand
Summary: This study synthesized hollow MoSe2--NiSe2 nanotubes anchored on carbon nanotubes using a hydrothermal method followed by an ultrasonication process, and developed them as efficient counter electrodes in dye-sensitized solar cells (DSSCs). The resulting nanocomposite showed high power conversion efficiency (PCE) and exceptional electrochemical durability, outperforming platinum-based cells.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Chemistry, Multidisciplinary
Qin Liu, Cunxi Cheng
Summary: The polypyrrole-cobalt sulfide composite counter electrode (PPy-CoS CE) prepared in this study exhibited superior photoelectric conversion efficiency in DSSC compared to platinum (Pt) CE. Additionally, the PPy-CoS CE demonstrated excellent catalytic performance for I-3(-)/I- solution based on cyclic voltammetry and electrochemical impedance spectroscopy measurements.
Article
Engineering, Electrical & Electronic
F. Z. Tighilt, S. Belhousse, K. Hamdani, Y. Abdallaoui, M. Melaine, H. Lallali, K. Lasmi, A. Manseri, N. Belhaneche, S. Sam
Summary: Uniform PPy films were prepared on fluorine doped tin oxide substrates using chronoamperometry technique and used as CEs in DSSCs. The efficiency of PPy polymerization was confirmed by FTIR and contact angle measurements. SEM images revealed the formation of unbounded PPy chains on the cauliflower structure at longer deposition times. The electrocatalytic activity of PPy films and the performance of PPy CE-based DSSCs decreased with increasing deposition time, likely due to higher ion diffusion resistance in the formed unbounded PPy chains.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Pooja A. Mithari, Avinash C. Mendhe, Swapnil S. Karade, Babasaheb R. Sankapal, Sujata R. Patrikar
Summary: The simple chemical bath deposition method successfully prepared MoS2 nanoflakes/MWCNTs thin-film composite material as the counter electrode in DSSCs, significantly increasing the photovoltaic conversion efficiency. The synergistic effect of the two materials resulted in improved electrocatalytic activity and lower charge transfer resistance at the CE/electrolyte interface.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Subashini Gnanasekar, Andrews Nirmala Grace
Summary: The use of vanadium pentoxide as a cost-effective counter electrode in dye-sensitized solar cells has shown good electrocatalytic activity with enhanced charge transfer kinetics, leading to a significant improvement in the overall performance compared to conventional Pt electrodes. Further research on nanostructures of V2O5 is encouraged for large-scale production as an alternative to Pt electrodes.
Article
Chemistry, Inorganic & Nuclear
Pooja A. Mithari, Avinash C. Mendhe, Suraj R. Sankapal, Sujata R. Patrikar, Babasaheb R. Sankapal
Summary: Bi2Se3 nanoparticles were anchored on multiwalled carbon nanotubes using the SILAR method to create a nanohybrid composite electrode for dye-sensitized solar cell applications. The well-optimized composite showed superior performance compared to bare MWCNTs and Bi2Se3, thanks to the synergistic electrochemical active sites between Bi2Se3 and MWCNTs. The composite electrode also exhibited enhanced stability and efficient charge transfer in the DSSC.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
J. Luo, J. C. Liu, Z. Q. Zhao, S. H. Sun, Y. Zhu, Y. M. Hu
Summary: Orthogonal Cu3SnS4 (CTS) nano-crystals were synthesized, with Cu7S4 seeds forming first at 130 degrees C and orthorhombic CTS nano-crystals forming at 180 degrees C. Selenization at 500 degrees C for 20 minutes resulted in the formation of CTSXSe4-X, which showed good conductivity and electrocatalytic activity for I-3(-) reduction when used as counter electrodes in dye-sensitized solar cells. The optimal 1.7 μm thick CTSXSe4-X counter electrode achieved a power conversion efficiency of 7.57%.
Article
Energy & Fuels
Erdi Akman, Hacer Sibel Karapinar
Summary: This study reports the production of selenium@activated carbon (Se@AC) composites as an alternative to platinum (Pt) for dye-sensitized solar cells. The Se@AC composite counter electrodes showed significantly enhanced electrocatalytic activity and charge transfer properties, resulting in a DSSC with performance close to that of the Pt-based reference. The cost-effective and facile production process of the Se@AC composite makes it an effective alternative to expensive Pt.
Article
Chemistry, Physical
Abdullah Yildiz, Takwa Chouki, Aycan Atli, Moussab Harb, Sammy W. Verbruggen, Rajeshreddy Ninakanti, Saim Emin
Summary: Transition metal phosphides, particularly the Fe2P phase, show comparable solar-to-current conversion efficiency with platinum (Pt) as a counter electrode in dye-sensitized solar cells (DSSCs) while exhibiting improved stability, making them a promising Pt-free alternative for efficient DSSCs.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Zhengfeng Zhu, Zhengmeng Lin, Yu Gu, Jiatian Song, Xinyue Kang, Hongyu Jiang, Huisheng Peng
Summary: Fiber solar cells, woven into textiles, have shown potential in supplying electricity for wearables. However, achieving high power conversion efficiencies in real-world applications remains a challenge. A unique hybrid counter electrode was designed using metal current collector fiber, aligned carbon nanotube sheet, and porous titanium dioxide/poly(vinylidene fluoride-co-hexafluoropropylene) film. This design achieved a record power conversion efficiency of 12.52% and maintained efficiency below 10% after bending, twisting, or pressing for 1000 cycles. The integration of these fiber dye-sensitized solar cells with fiber batteries demonstrated an effective power solution for wearables.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Md. Mahbubur Rahman
Summary: The novel nickel nitroprusside (NNP) nanoparticles incorporated with graphene nanoplatelets (GnP) were successfully utilized as a low-cost and effective counter electrode (CE) in dye-sensitized solar cells (DSSCs). This nanohybrid CE showed significantly improved electrocatalytic behavior for redox reactions and achieved a comparable photovoltaic performance to the reference Pt-CE, demonstrating its potential as a suitable replacement for Pt-CE in DSSCs.
Article
Chemistry, Inorganic & Nuclear
Javad B. M. Parambath, Mahreen Arooj, Maria Omastova, Mohamed M. Chehimi, Sanghyun Kim, Changseok Han, Ahmed A. Mohamed
Summary: In this study, graphene oxide was decorated with gold-aryl nanoparticles by reducing aryldiazonium tetrachloroaurate(III) salt with sodium borohydride at room temperature. The resulting gold-aryl/graphene oxide nanocomposite exhibited a rough and wrinkled surface. X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller measurements confirmed the successful anchoring of gold nanoparticles on graphene oxide and a decrease in surface area of the nanocomposite.
JOURNAL OF CLUSTER SCIENCE
(2023)
Article
Engineering, Environmental
Laszlo Lendvai, Maria Omastova, Amar Patnaik, Gabor Dogossy, Tej Singh
Summary: This study explores the possibility of developing a new class of hybrid biocomposites using wood flour and rice husk as environmentally friendly additives to PLA. The results show that the addition of natural waste particles significantly improves the mechanical properties of the material but decreases its impact strength and tensile strength. Limited interfacial adhesion between the components is observed, and the particles act as nucleating agents, increasing the overall crystallinity of the material.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Chemistry, Physical
Matej Micusik, Miroslav Slouf, Anastasiia Stepura, Yaryna Soyka, Evgeni Ovodok, Michal Prochazka, Maria Omastova
Summary: This study investigates the stability of Ti3C2OxFx MXene in air and argon. X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) are used to study the chemical and morphological changes in MXene over time. The presence of water is found to play a crucial role in the aging process of MXene.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Applied
Marek Hasso, Ivana Matuskova, Lubomir Svorc
Summary: This paper introduces a new and rapid electroanalytical sensing platform for the quantification of theobromine in food products. The method utilizes batch injection analysis with amperometric detection on screen-printed carbon electrodes. The method has several advantages including minimal sample manipulation, wide linear concentration range, and high analytical frequency.
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
(2023)
Article
Chemistry, Analytical
Sladana Durdic, Filip Vlahovic, Milan Markicevic, Jelena Mutic, Dragan Manojlovic, Vesna Stankovic, L'ubomir Svorc, Dalibor Stankovic
Summary: A screen-printed diamond electrode coupled with a point-of-care platform was used for the electrochemical determination of pterostilbene. The oxidation of pterostilbene was found to be pH-dependent, and the most probable reactive site of the analyte was determined using DFT-based reactivity descriptors. The optimized differential pulse voltammetry method showed excellent selectivity and nanomolar-level detection limits for pterostilbene.
Article
Nanoscience & Nanotechnology
Denis Zabelin, Kamil Severa, Jaroslav Kulicek, Bohuslav Rezek, Anastasiia Tulupova, Roman Elashnikov, Anna Zabelina, Vasilii Burtsev, Petr Sajdl, Elena Miliutina, Vaclav Svorcik, Oleksiy Lyutakov
Summary: In this study, a specific structure based on WO3-x/CdWO4/CdS coupled semiconductors was proposed and prepared. The structure, created by annealing a commonWO(3)/CdS direct Z-scheme, was further combined with a plasmon-active grating to achieve the artificial leaf design and complete utilization of the sunlight spectrum. The proposed structure enables efficient water splitting without catalyst photodegradation.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Inorganic & Nuclear
Milan Piros, Martin Schoeller, Katarina Konarikova, Jindra Valentova, Lubomir Svorc, Jan Moncol, Marian Valko, Jozef Svorec
Summary: In this study, five heteroligand copper(II) complexes with diethylnicotinamide and various fenamates were synthesized and characterized. The complexes exhibited antioxidant and anticancer activities, and interacted with DNA and serum albumin. Among them, complex 4 showed moderate anticancer activity against MCF-7 cancer cells.
Article
Polymer Science
Michaela Pavlickova, Sladana Durdic, Michal Hatala, Dalibor Stankovic, Lubomir Svorc, Peter Veteska, Pavol Gemeiner
Summary: This study demonstrates the preparation of pad-printable inks containing reduced graphene oxide (rGO) and cellulose-based polymers (ethylcellulose and cellulose acetate butyrate) for pad printing. The most suitable polymer concentrations for pad printing are determined based on rheological parameters and printability analysis. The resulting rGO electrodes, printed with ethylcellulose as a binder, show good performance in detecting ascorbic acid.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Analytical
Marek Hasso, Olha Sarakhman, Sladana Durdic, Dalibor Stankovic, Lubomir Svorc
Summary: An advanced electrochemical platform was developed for the determination of tannic acid in beverages. The optimal experimental parameters were evaluated, and the platform showed advantages such as portability, low sample consumption, simple sample preparation, high sampling frequency, low limit of detection, and suitable precision. The method was successfully applied to analyze beverage samples and achieved high recovery values for tannic acid.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Olha Sarakhman, Nadine Wenninger, Anita Rogala, Lubomir Svorc, Kurt Kalcher, Astrid Ortner
Summary: A state-of-the-art strategy for lipase activity determination in pancreatic preparations using FIA-ED was described. The optimized method showed good correlation with the titrimetric method and manufacturer's declaration. The procedure allowed for the determination of lipase activity in a range of 0.8 to 18 U L-1 with LOD and LOQ values of 0.3 U L-1 and 1 U L-1, respectively.
Article
Environmental Sciences
Sladana Durdic, Filip Vlahovic, Pavol Gemeiner, Olha Sarakhman, Vesna Stankovic, Jelena Mutic, Dalibor Stankovic, Milos Ognjanovic, Lubomir Svorc
Summary: In this study, a nanocomposite based on Co-doped CeO2 nanoparticles embedded into graphitic carbon nitride was developed and applied to functionalize commercial glassy carbon paste. The electrochemical sensor based on this nanocomposite was utilized for the detection and quantification of organophosphate pesticide fenitrothion. The oxidation and reduction processes of fenitrothion were experimentally observed and theoretically modeled, leading to a detailed understanding of its redox mechanism. The developed sensor exhibited nanomolar detection limit, wide linear concentration range, and good precision, repeatability, and selectivity towards fenitrothion. Furthermore, the sensor showed great potential for real-time monitoring of fenitrothion traces in environmental samples.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Chemistry, Analytical
Jana Sadecka, Michaela Jakubikova, Katarina Hrobonova, Lubomir Svorc, Marek Hasso
Summary: Non-targeted UV-Vis/SF spectroscopic and DPV fingerprinting were used to discriminate between caramel-containing and caramel-free wine spirits. High correct classification rates were achieved using VIP-PLS-DA and VIP-PCA-LDA analysis. The conclusions were verified by targeted HPLC-DAD analysis.
MICROCHEMICAL JOURNAL
(2023)
Article
Nanoscience & Nanotechnology
Nikhitha Joseph, Haojie Fei, Constantin Bubulinca, Marek Jurca, Matej Micusik, Maria Omastova, Petr Saha
Summary: This study modifies the TNO15 material by introducing oxygen vacancies and using carbon and copper coatings on the surface to improve its lithium ion storage performance. The carbon/copper coated TNO15 has a higher diffusion coefficient and better conductivity. The prepared half-cell shows a significant rate capability at high current densities, and the TNO15 nanoparticles with carbon and copper coatings form a porous microsphere structure for better lithium ion transportation.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Katerina Skopalova, Itana Nusa Bubanja, Dragomir Stanisavljev, Nikola Cvjeticanin, Vera Kasparkova, Eliska Dad'ova, Erika Pavlikova, Marek Koutny, Marija Gizdavic-Nikolaidis, Petr Humpolicek
Summary: This study compares the biological properties of PANI prepared by different synthesis methods and oxidizing agents, which improves its potential applications in the biomedical field.
Article
Materials Science, Multidisciplinary
Hui-Ping Li, Cai-Yan Gao, Zhi-Ping Chen, Xin-Heng Fan, Lian-Ming Yang
Summary: In this study, a novel type of D-A non-fused-ring copolymers was designed and synthesized to overcome the trade-off relationship between electrical conductivity and Seebeck coefficient in organic semiconductors. The incorporation of fluorine atoms into the polymer backbone effectively increased the ordered degree of molecular stacking and improved both the electrical conductivity and Seebeck coefficient. The bimodal orientation of polymers played a crucial role in decoupling the correlation between electrical conductivity and Seebeck coefficient.
Article
Materials Science, Multidisciplinary
Mansour A. S. Salem, Amjad Mumtaz Khan, Hatem A. M. Saleh, Khalil M. A. Qasem, Mizna Ahmed, Aadil Shafi Bhat, Abdulaziz Abdullah Qasem Ali, Younes S. A. Ghanem, Ali Alrabie, Abdel-Basit Al-Odayni, Waseem Sharaf Saeed, Basheer Al-Anesi
Summary: This research focuses on the versatile substance, polyaniline/layered double hydroxide (PANI@Nd-Co/LDH), under solvothermal conditions. A thorough analysis of its structure and morphology was conducted using various analytical methods. The findings showed that PANI@Nd-Co/LDH exhibited highly sensitive and specific fluorescence detection of Pb(II) and Al(III), outperforming other heavy metal ions. The sensor demonstrated a turn-off fluorescence response for Pb(II) ions and a turn-on fluorescence response for Al(III) ions. The minimum detectable limits (MDL) were determined to be 9.6 nM for Pb(II) and 220 nM for Al(III). PANI@Nd-Co/LDH could be easily regenerated and reused for multiple cycles. The detection mechanisms involved the inner filter effect (IFE) for Pb(II) and the chelation-enhanced fluorescence (CHEF) effect for Al(III). These results highlight the excellent potential of PANI@Nd-Co/LDH in the detection and recognition of Pb(II) and Al(III) ions.