Journal
SYNTHESIS-STUTTGART
Volume 47, Issue 11, Pages 1534-1546Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380548
Keywords
Julia olefination; fluoroalkenes; difluoroalkenes; trifluoromethyl-substituted alkenes; fluorinated enol ethers
Categories
Funding
- University Lyon 1
- CNRS
- excellence laboratory LabEx SYNORG [ANR-11-LABX-0029]
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The modified Julia olefination is now a powerful tool for the synthesis of a large range of functionalized alkenes. This short review covers the last five years and provides an overview of the synthesis of mono-, difluoro-, and trifluoromethyl-substituted alkenes via the modified Julia olefination focusing on the novel scope of this reaction. 1 Introduction 2 Monofluoroalkenes 2.1 Disubstituted alpha- and beta-Monofluoroalkenes 2.2 Bis(trifluoromethyl) phenyl Sulfones 2.3 Conjugated Monofluoroalkenes 2.4 Intramolecular Julia Olefination 2.5 Smiles Rearrangement from Fluorinated Keto Sulfones 2.6 Fluoroallylamines 2.7 Fluorinated exo-Glycals 2.8 Monofluoroalkenes with an alpha-Stereocenter at the Allylic Position 3 1,1-Difluoroalkenes 4 Trifluoromethyl-Substituted Alkenes 5 Conclusion
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