Journal
SYNLETT
Volume 26, Issue 20, Pages 2843-2848Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560637
Keywords
palladium-catalyzed; acetoxylation-alkoxylation; C-H bond cleavage; azoxybenzene; regioselective
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Funding
- Northwest University [NF14020]
- Education Department of Shaanxi Provincial Government [14JK1735]
- National Found for Fostering Talents of Basic Science [NFFTBS-J1103311, J1210057]
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Efficient strategies for the regioselective ortho acetoxylation/alkoxylation of C-H bond of azoxybenzenes in the presence of palladium catalysts were developed using PhI(OAc)(2) as the teminal oxidant. Under the very similar conditions established, both reactions proceeded smoothly and were tolerated by a variety of functional groups.
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