4.4 Article

Osmium on Chelate Resin: Nonvolatile Catalyst for the Synthesis of Diols from Alkenes

Journal

SYNLETT
Volume 26, Issue 5, Pages 700-704

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379990

Keywords

chelate resin; diols; osmium; oxidation; supported catalyst

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Osmium tetraoxide (OsO4) was immobilized on a commercially available chelate resin DIAION CR11 (CR11) just by simply immersing it in a methanol solution of OsO4 at room temperature. The resulting purple solid, 5% Os/CR11, indicated no volatility, and effectively catalyzed the oxidation of various alkenes to the corresponding diols.

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