Journal
SYNLETT
Volume 26, Issue 5, Pages 700-704Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379990
Keywords
chelate resin; diols; osmium; oxidation; supported catalyst
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Osmium tetraoxide (OsO4) was immobilized on a commercially available chelate resin DIAION CR11 (CR11) just by simply immersing it in a methanol solution of OsO4 at room temperature. The resulting purple solid, 5% Os/CR11, indicated no volatility, and effectively catalyzed the oxidation of various alkenes to the corresponding diols.
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