4.3 Article

Investigation of nano-size montmorillonite on electron beam irradiated flame retardant polyethylene and ethylene vinyl acetate blends

Publisher

ELSEVIER
DOI: 10.1016/j.nimb.2013.01.040

Keywords

Electron beam irradiation; Montmorillonite; Flame retardant; Ethylene vinyl acetate; Electrical properties; Mechanical properties

Funding

  1. Research University Grant of Universiti Teknologi Malaysia

Ask authors/readers for more resources

This study aims at investigating the effects of montmorillonite (MMT) and electron beam irradiation on alumina trihydrate (ATH) added low density polyethylene and ethylene vinyl acetate (LOPE-EVA) blends. The nano-size MMT was used to improve the flammability and mechanical properties of the ATH added LDPE-EVA blends. The samples were irradiated at the dosage range 0-250 kGy using electron beam accelerator. The limiting oxygen index test (LOI) revealed that the incorporation of MMT into ATH added LOPE-EVA blends could improve the flammability up to 28.4 LOI%. The application of irradiation effect also improved the flame retardancy of the blends for similar to 2 LOI% compared to un-irradiated samples. The addition of MMT loading levels from 10 to 20 phr exhibited reinforcing effect for 10.3-14.6% in tensile strength. On the other hand, the increasing of MMT loading levels has gradually decreased the surface and volume resistance of ATH added LDPE-EVA blends. The increase in irradiation dosages from 0 to 150 kGy was found to slightly decrease the surface and volume resistivity of the ATH added LDPE-EVA samples especially at high loading of MMT. The enhancement of mobility of MMT ionic in polymer matrix could lead to the reduction of the surface and volume resistivity. Consequently, this study has demonstrated that addition of MMT and electron beam irradiation to ATH added LDPE-EVA blends have resulted better flammability, mechanical and electrical properties of ATH added LDPE-EVA blends. (C) 2013 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.3
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Biochemistry & Molecular Biology

Gamma-Irradiation Induced Functionalization of Graphene Oxide with Organosilanes

Kabiru Musa Aujara, Buong Woei Chieng, Nor Azowa Ibrahim, Norhazlin Zainuddin, Chantara Thevy Ratnam

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2019)

Article Chemistry, Applied

Interactive effects of carbon nanotube and montmorrilonite reinforcement polyvinyl alcohol composite system

Soo-Tueen Bee, Lee Tin Sin, Nicole Ooi Ker Qi, Chantara Thevy Ratnam, A. R. Rahmat

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2020)

Review Materials Science, Composites

Mechanical properties of wollastonite reinforced thermoplastic composites: A review

Jia X. Chan, Joon F. Wong, Azman Hassan, Zurina Mohamad, Norhayani Othman

POLYMER COMPOSITES (2020)

Article Engineering, Chemical

Wood Plastic Composites Produced from Postconsumer Recycled Polystyrene and Coconut Shell: Effect of Coupling Agent and Processing Aid on Tensile, Thermal, and Morphological Properties

Sing Li Ling, Seong Chun Koay, Ming Yeng Chan, Kim Yeow Tshai, Thevy Ratnam Chantara, Ming Meng Pang

POLYMER ENGINEERING AND SCIENCE (2020)

Article Polymer Science

Synthesis of surface ion-imprinted polymer for specific detection of thorium under acidic conditions

N. A. F. Othman, S. Selambakkannu, H. Azian, C. T. Ratnam, T. Yamanobe, H. Hoshina, N. Seko

Summary: A fibrous surface ion-imprinted polymer (IIP) was successfully synthesized for the selective removal of thorium ions from aqueous solution. The polymer was prepared through direct electron beam radiation using thorium as a template. The IIP showed promising removal efficiency and is a potential material for thorium removal applications.

POLYMER BULLETIN (2021)

Article Materials Science, Composites

Surface-treated short sisal fibers and halloysite nanotubes for synergistically enhanced performance of polypropylene hybrid composites

Prakash Krishnaiah, Sivakumar Manickam, Chantara Thevy Ratnam, M. S. Raghu, L. Parashuram, K. Prashantha, Byong-Hun Jeon

Summary: In this study, polypropylene composites were prepared by reinforcing with short sisal fibers treated with alkali and high-intensity ultrasound, as well as halloysite nanotubes modified with 3-aminopropyltriethoxysilane. The synergistic effect between the surface-treated fibers and the modified nanotubes was evaluated through various characterization techniques. The results showed that the treatments significantly enhanced the interaction between the fillers and the matrix, leading to improved mechanical, dynamic mechanical, and thermal properties of the composites.

JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS (2022)

Review Materials Science, Multidisciplinary

Thermal and flammability properties of wollastonite-filled thermoplastic composites: a review

Wong Joon Fatt, Chan Jia Xin, Azman Hassan, Zurina Mohamad, Norhayani Othman

Summary: Wollastonite has the potential to enhance mechanical strength, thermal stability, and flame retardancy in thermoplastic composites, attracting academia and industry attention. Research focuses on the effects of wollastonite incorporation into polymers and its potential applications, particularly in terms of thermal and flammability properties. Further investigation of nano-sized synthetic wollastonite and hybrid wollastonite/nanofillers is suggested for the development of high-performance materials.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Polymer Science

Synergistic effects of hybrid nanofillers on graphene oxide reinforced epoxy coating on corrosion resistance and fire retardancy

Siti Maznah Kabeb, Azman Hassan, Faiz Ahmad, Zurina Mohamad, Zalilah Sharer, Munirah Mokhtar

Summary: This study investigated the synergistic effects of hybrid nanofillers on the anticorrosion and flame retardancy properties of graphene oxide reinforced epoxy coatings. Testing methods included EIS, Tafel polarization, SST, LOI, and TEM to reveal the improvements in corrosion resistance and burning behavior. The results showed that hybrid nanofillers enhanced the barrier properties of the coatings, leading to better performance in both corrosion protection and flame retardancy.

JOURNAL OF APPLIED POLYMER SCIENCE (2022)

Article Polymer Science

Mechanical properties of rice husk and rice husk ash filled maleated polymers compatibilized polypropylene composites

Obinna E. Ezenkwa, Azman Hassan, Sani A. Samsudin

Summary: The study found that rice husk imparts better reinforcing effect in PP composite than rice husk ash, while MAPP is a better compatibilizer. SEM study indicates that both compatibilizers improved the filler-matrix interfacial adhesion.

JOURNAL OF APPLIED POLYMER SCIENCE (2022)

Article Materials Science, Composites

Use of synthetic wollastonite nanofibers in enhancing mechanical, thermal, and flammability properties of polyoxymethylene nanocomposites

Joon Fatt Wong, Jia Xin Chan, Azman Hassan, Zurina Mohamad, Shahrir Hashim, Jeefferie Abd Razak, Yern Chee Ching, Zaini Yunos, Ridwan Yahaya

Summary: This study investigates the properties of synthetic wollastonite nanofibers reinforced polyoxymethylene nanocomposites. The results showed that the mechanical strength, thermal stability, and flame retardancy of the nanocomposites were improved, indicating their potential use in automotive applications.

POLYMER COMPOSITES (2022)

Article Polymer Science

Mechanical, thermal, tribological, and flammability properties of polybutylene terephthalate composites: Comparing the effects of synthetic wollastonite nanofibers, natural wollastonite, and graphene oxide

Jia Xin Chan, Joon Fatt Wong, Azman Hassan, Norhayani Othman, Jeefferie Abd Razak, Umar Nirmal, Shahrir Hashim, Yern Chee Ching, Muhamad Zaini Yunos, Ridwan Yahaya, T. M. Sampath U. Gunathilake

Summary: The effects of different fillers on the properties of PBT composites were studied. It was found that PBT/SWN had the highest tensile strength and Young's modulus, PBT/GO showed the best wear resistance and anti-friction performance, while PBT/NW had the lowest heat release rate and smoke production rate.

JOURNAL OF APPLIED POLYMER SCIENCE (2023)

Article Materials Science, Composites

Effect of aspect ratio of synthetic Wollastonite nanofibers on mechanical, thermal and flammability properties of polyoxymethylene nanocomposites

Joon Fatt Wong, Jia Xin Chan, Azman Hassan, Zurina Mohamad, Shahrir Hashim, Jeefferie Abd Razak, Yern Chee Ching, Muhamad Zaini Yunos, Ridwan Yahaya, T. M. Sampath U. Gunathilake

Summary: Polyoxymethylene (POM) nanocomposites reinforced with synthetic wollastonite nanofibers (SWN) showed improved mechanical, thermal, and flammability properties as the aspect ratio of SWN increased. Higher aspect ratio SWN resulted in increased tensile strength, Young's modulus, and impact strength in POM nanocomposites. However, lower aspect ratio SWN performed better in flame retardancy, with delayed time to ignition and decreased peak heat release rate.

POLYMER COMPOSITES (2023)

Article Multidisciplinary Sciences

Compatibilization of Poly (lactic acid)/Polycarbonate Blends using Triacetin-mediated Interchange Reactions

Ashish Kumar, Azman Hassan, Mohd Yazid Yahya, Abdul Hadi Azman

Summary: The aim of this study was to improve the properties of PLA by blending it with PC using melt blending technique. The effects of TA as compatibilizers and TBATPB as catalyst were investigated. The addition of triacetin and catalyst resulted in the best mechanical properties, confirming the synergistic action promoted the transesterification reaction between PLA and PC, enhancing the compatibility of the PLA/PC system.

MALAYSIAN JOURNAL OF FUNDAMENTAL AND APPLIED SCIENCES (2023)

Article Engineering, Multidisciplinary

THERMAL, DYNAMIC MECHANICAL ANALYSIS AND MECHANICAL PROPERTIES OF POLYBUTYLENE TEREPHTHALATE/POLYETHYLENE TEREPHTHALATE BLENDS

Muhammad Akmal Ahmad Saidi, Azman Hassan, Mat Uzir Wahit, Lai Jau Choy, Hazleen Anuar

JURNAL TEKNOLOGI-SCIENCES & ENGINEERING (2020)

Article Engineering, Multidisciplinary

EFFECT OF CHITIN SOURCE AND CONTET ON PROPERTIES OF CHITIN NANOWHISKERS FILLED POLYLACTIC ACID COMPOSITES

Syazeven Effatin Azma Mohd Asri, Zainoha Zakaria, Azman Hassan, Mohamad Haafiz Mohamad Kassim

IIUM ENGINEERING JOURNAL (2020)

Article Instruments & Instrumentation

X-ray-Induced scintillation properties of Cr-Doped Mg4Ta2O9 single crystals in Near-Infrared regions

Taisei Hayashi, Kensei Ichiba, Daisuke Nakauchi, Takumi Kato, Noriaki Kawaguchi, Takayuki Yanagida

Summary: In this study, Cr-doped Mg4Ta2O9 single crystals with different doping levels were synthesized using the floating zone method, and their photoluminescence and scintillation properties were evaluated. The results showed that Cr-doped Mg4Ta2O9 single crystals exhibited broad emission bands in the near-infrared region and showed scintillation characteristics within specific wavelength ranges. Additionally, the samples with different Cr doping levels demonstrated different lower detection limits based on the dose rate response function.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)

Article Instruments & Instrumentation

Monte Carlo simulation of electron emission from aluminum after low energy protons impact

S. Marouf, A. C. Chami, Y. Boudouma

Summary: This study develops a Monte Carlo simulation approach to describe proton-induced secondary electron emission in solids. Theoretical modeling based on the Mott's elastic scattering cross-section and Lindhard's dielectric function was used to calculate the double differential cross-section (DDCS) of excited electrons and describe electron transport in the medium. The results for aluminum show the angular and energy distributions of backscattered electrons for incident protons with energy below 25 keV at normal incidence, and the total electron emission yield also agrees well with available measurements.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)

Article Instruments & Instrumentation

Organic-inorganic hybrid perovskite scintillator for high-resolution X-ray imaging

Weipeng Yan, Baojun Duan, Zijian Zhu, Yan Song, Guzhou Song, Jiming Ma, Binkang Li, Yucheng Liu

Summary: This article reports on the scintillation performance of Lithium-doped 2D (PEA)2PbBr4 perovskite single crystals synthesized at room temperature. The crystals exhibit fast decay time, high light yield, and high spatial resolution, making them highly promising for medical diagnostic applications.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)

Article Instruments & Instrumentation

Influence of thermal annealing on silicon negative ion implanted SiO2 thin films

S. B. Vishwakarma, S. K. Dubey, R. L. Dubey, I. Sulania, D. Kanjilal

Summary: Investigations have been conducted on the implanted SiO2 thin film after thermal annealing using various analytical techniques. The results revealed the absence of vacancy defects, variations in vibrational modes and the formation of new structures. The photoluminescence intensity of the annealed SiO2 samples was higher, with a decrease in non-radiative defect centers and an increase in radiative Si:SiO2 interface states. Additionally, the presence of silicon nanoclusters formed after annealing resulted in an additional radiative recombination peak. Furthermore, the formation of new SiOx structures was observed after thermal annealing.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)

Article Instruments & Instrumentation

Linear energy transfer dependence of scintillation properties of CeF3

M. Koshimizu, S. Kurashima, A. Kimura, M. Taguchi

Summary: By observing the scintillation time profiles of CeF3 under irradiations of pulsed beams with different LETs, we found that the initial decay was faster for higher LET, which is consistent with previous studies on other self-activated scintillators. This faster decay at higher LET can be explained by the competition between the scintillation caused by 5d-4f transition of Ce3+ ions and quenching due to the interaction between excited Ce3+ ions close to each other.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)

Article Instruments & Instrumentation

Study on the production of hydrogen atomic beams by stripping negative hydrogen ions in a gas target

Junjie Shi, Jianhong Hao, Fang Zhang, Qiang Zhao, Bixi Xue, Jieqing Fan, Zhiwei Dong

Summary: This study examined the neutralization process and beam quality of a hydrogen beam by emitting negative hydrogen ions to a hydrogen target. The findings showed that the neutralization efficiency was influenced by variables such as the transport distance, energy, and target gas density. However, the maximal neutralization efficiency was not affected by the density of the target gas or the energy of the negative hydrogen ions.

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (2024)