Journal
NEW JOURNAL OF CHEMISTRY
Volume 37, Issue 2, Pages 309-316Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj40625j
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Funding
- National Natural Science Foundation of China [20901037]
- Program for New Century Excellent Talents in Fujian Province University [JK2010043]
- Undergraduate Innovative Research Program of Fujian Province [mjcx1102]
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The biocompatible organic acids such as acetic acid (Hac), benzoic acid (Hbz) and nicotinic acid (Hnit), have been employed as second ligands to assemble biocompatible coordination polymers of theophylline (Hthp), respectively. As a result, three coordination polymers [Zn-2(thp)(2)(ac)(OH)](n) (1), [Zn-2(thp)(2)(bz)(OH)](n) (2) and [Zn(thp)(nit)](infinity) (3) have been synthesized through hydrothermal and mechanochemical reactions. Theophylline could be released rapidly in simulated gastroenteric fluid (phosphate-buffered solution, PBS) and slow release of theophylline could be achieved from the three polymers in pure water at 37 degrees C with continuous stirring.
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