Journal
NEW JOURNAL OF CHEMISTRY
Volume 36, Issue 6, Pages 1378-1384Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nj21073h
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Funding
- Natural Science Foundation of China [21107071]
- Shanghai Government [07dz22303, S30406, 10dj1400100, 10PJ1408200, 11YZ88, ssd10014]
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Multifunctional mesoporous material (NH2&Ph-SBA-15) was synthesized by co-condensation of tetraethyl orthosilicate, amine-silane and phenyl-silane in the presence of triblock copolymer P123. The Pd nanoparticles immobilized on the NH2&Ph-SBA-15 support were fabricated by the impregnation and subsequent reduction method. The XRD, TEM, N-2 sorption, IR and solid NMR measurements revealed that this novel mesoporous Pd catalyst (Pd/NH2&Ph-SBA-15) not only maintained ordered hexagonal mesopores, but also possessed characteristics of the two organic functional groups on the mesopore surface. Compared with Pd nanoparticles supported on the parent SBA-15 or monofunctionalized mesoporous materials, it displayed much higher catalytic reactivity and selectivity in the water-medium Ullmann reaction. This could be attributed to the synergic promoting effect derived from binary organic functional groups since the NH2-groups led to the uniform dispersion of Pd nanoparticles inside the pore channels while the Ph-groups decreased the diffusion limitation of organic molecules in water. Furthermore, it could be conveniently recovered and recycled six times without significant loss of activity and selectivity.
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