Article
Chemistry, Inorganic & Nuclear
Zhifo Guo, Xiangyang Lei
Summary: The new catalytic system using Ni(NO3)(2)center dot 6H(2)O as catalyst and a pincer pyrrole-functionalized N-heterocyclic carbene as ligand showed high efficiency in Suzuki-Miyaura cross-coupling reactions of aryl iodides with arylboronic acids, yielding high isolated yields of coupling products in short reaction times. The system worked well with aryl iodides bearing electron-donating or electron-withdrawing groups and arylboronic acids with electron-donating groups, while steric effects were observed for both aryl iodides and arylboronic acids.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2021)
Article
Materials Science, Paper & Wood
Arnet Maria Antony, Masira Imtiyaz Chamanmalik, Vishal Kandathil, Harini G. Sampatkumar, B. S. Sasidhar, C. V. Yelamaggad, Siddappa A. Patil
Summary: A new N-heterocyclic carbene-palladium(II) complex grafted on cellulose was synthesized as a heterogeneous catalyst. The structure, morphology, thermal stability and chemical composition of the catalyst were confirmed by various analytical techniques. The catalyst exhibited excellent catalytic ability in Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions, with good tolerance to various functional groups and easy recovery by filtration.
Article
Chemistry, Multidisciplinary
Deepak Gautam, Puneet Singh Gahlaut, Kapil Yadav, Barun Jana
Summary: The intermingling of a novel imidazolium salt (HL1-Br) and Cu(OAc)(2) has been found to be a highly efficient catalytic system for Buchwald-Hartwig-type C-N coupling of various amines with (hetero) aryl bromides/chlorides. This system allows for the reaction to proceed under base-, solvent-, and inert-gas-free conditions, providing a broad range of substrates with good to excellent yields and offering innovative solutions for challenges in catalytic, synthetic chemistry, and drug discovery research.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Yu-Yang Zhou, Yang-Ming Ding, Wei Zhao, Jian-Hua Dong, Liang-Zhi Li, Hong-Yuan Chen, Jing-Juan Xu
Summary: Three new ruthenium(ii) complexes with N-heterocyclic carbene ligands have been synthesized and shown to be efficient near-infrared ECL luminophores. These complexes demonstrate higher or comparable ECL efficiency compared to traditional Ru(bpy)(3)(2+), indicating great potential for future applications in NIR ECL imaging.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Organic
Tingting Liu, Yucai Hu, An Shen
Summary: The structure of ligands is crucial in carbon-carbon coupling reactions catalyzed by N-heterocyclic carbene palladium (NHC-Pd) complexes. Both the modification of NHC ligands and the synergistic action of the second ligands are required for better catalytic performance. However, the synergistic effect of the second ligands is often overlooked due to their weaker coordination ability. This study utilized three NHC-Pd complexes with the same NHC ligand but different imine ligands to catalyze the Suzuki-Miyaura cross-coupling reaction. The results showed significantly different catalytic effects, and theoretical calculations were used to investigate the catalytic mechanism.
CHINESE JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Javier Ruiz, Maria A. Mateo
Summary: An isocyanide-functionalized imidazole was synthesized from 4-(1H-imidazol-1-yl)aniline using the Ugi method, and subsequently converted into the corresponding imidazolium salt. Coordination of the isocyanide residue allowed the synthesis of several transition metal complexes containing a peripheral imidazolium cation, which serve as suitable starting materials for the formation of mixed ligand isocyanide-NHC heterometallic complexes.
DALTON TRANSACTIONS
(2022)
Article
Biochemistry & Molecular Biology
Mirko Ruamps, Stephanie Bastin, Lionel Rechignat, Alix Sournia-Saquet, Laure Vendier, Noel Lugan, Jean-Marie Mouesca, Dmitry A. Valyaev, Vincent Maurel, Vincent Cesar
Summary: The coordination chemistry of the N-heterocyclic carbene ligand IMes((NMe2)2), and its interaction with transition metal centers, was investigated. The redox behavior of the resulting organometallic complexes was studied, revealing the different oxidation states and their effects on the donating properties of the ligand.
Article
Chemistry, Physical
Ricardo J. Alves, Laize Zaramello, Elvis N. Nishida, Frank H. Quina, Bruno S. Souza
Summary: In this study, we investigated the transient formation of N-heterocyclic carbenes (NHCs) in zwitterionic imidazolium sulfonate surfactants in a water environment. The formation of NHCs was accelerated above the critical micelle concentration, due to increased local concentration of hydroxide or deuteroxide ions. The rate of NHC formation could be controlled by the anions of added salts, which also affected the selectivity of anion binding to the micelle surface. The NHCs generated at the micelle surface promoted the selective oxidation of 4-nitrobenzaldehyde, demonstrating the importance of micellar microenvironment in controlling reactivity and selectivity in aqueous media.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Multidisciplinary Sciences
Lara E. Zetzsche, Jessica A. Yazarians, Suman Chakrabarty, Meagan E. Hinze, Lauren A. M. Murray, April L. Lukowski, Leo A. Joyce, Alison R. H. Narayan
Summary: This study demonstrates the use of cytochrome P450 enzymes for biocatalytic cross-coupling reactions, enabling the formation of sterically hindered biaryl bonds through oxidative C-C bond formation. By engineering the substrate and atroposelectivity of the P450 enzyme, a highly efficient and selective process has been developed.
Article
Chemistry, Multidisciplinary
Yahao Dong, Fengjun Xue, Yuping Wei
Summary: This study designed and prepared an eco-friendly magnetic palladium catalyst with excellent catalytic activity, easy recovery, high thermal stability, and low toxicity, providing new possibilities for the application of magnetic materials in green organic catalysis.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Review
Chemistry, Inorganic & Nuclear
Moushakhi Ghosh, Shabana Khan
Summary: This article highlights the recent developments in silylene-coinage metal chemistry, focusing on synthetic approaches, unusual properties, and catalytic efficiency of these complexes. Further research is needed to explore the potential of silylene-coinage metal complexes in various chemical reactions.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Organic
Peng Lei, Yibo Wang, Caixia Zhang, Yuge Hu, Juntao Feng, Zhiqing Ma, Xili Liu, Roman Szostak, Michal Szostak
Summary: In this study, the Sonogashira cross-coupling of aryl ammonium salts was successfully catalyzed by [Pd(NHC)(3-CF3-An)Cl2]. The catalyst exhibited broad scope and excellent C-N activation selectivity. The replacement of pyridine with aniline as an ancillary ligand in the Pd(II)-NHC complex was proven to be highly effective in stabilizing the catalyst.
Article
Chemistry, Inorganic & Nuclear
Bagmita Bhattacharyya, Amlan Jyoti Kalita, Ankur Kanti Guha, Nayanmoni Gogoi
Summary: A new N-heterocyclic carbene (NHC) ligand with a pendant phosphonate ester group was used to prepare two NHC-Pd(II) complexes and their catalytic efficacies in Suzuki-Miyaura cross-coupling reactions were investigated. The role of phosphonate ester or phosphonic acid substituents on the catalytic efficacy was decoded through DFT calculations.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Organic
Jiwei Wang, Xiang Cheng, Ye Liu, Jun Zhang
Summary: A variety of novel chiral and achiral 4,5-disubstituted 1-aryl-3-alkyl-imidazolium salts were synthesized through multicomponent reactions. Additionally, two novel unsymmetrical bulky cycloalkyl-based NHC-Pd complexes exhibited high catalytic activity in Suzuki-Miyaura and Negishi cross-coupling reactions.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Crystallography
Lixin You, Rui Tan, Xiaojuan Wang, Jianhong Hao, Shiyu Xie, Gang Xiong, Fu Ding, Andrei S. Potapov, Yaguang Sun
Summary: In this study, a new heterogeneous catalyst Pd-NHC@Eu-BCI was synthesized by incorporating N-heterocyclic carbene-palladium active sites into a 2D coordination polymer based on a 1,3-bis(carboxymethyl)imidazolium ligand. The catalyst was thoroughly characterized using various analytical techniques. The Pd-NHC@Eu-BCI catalyst exhibited excellent catalytic activity in the Suzuki-Miyaura cross-coupling reaction. It could be easily recovered from the reaction mixture and maintained its catalytic activity and structure even after five cycles.
Article
Chemistry, Physical
Jorge Meijide Suarez, Olivia Bistri-Aslanoff, Sylvain Roland, Matthieu Sollogoub
Summary: Encapsulation of metal centers inside cyclodextrins allows for control of coordination modes depending on cavity size and nature. The NHC ligands exhibit extraverted or introverted conformations in different sized CD cavities, influencing the behavior of metal complexes.
Article
Chemistry, Multidisciplinary
Andrea Mascherpa, Nozomii Ishii, Ayelen Tayagui, Jiang Liu, Matthieu Sollogoub, Antony J. J. Fairbanks
Summary: Beta-cyclodextrin and its derivatives have been approved for therapeutic use in over 30 clinical settings. They show promise as therapeutics for lysosomal storage disorders and other diseases involving metabolite accumulation in the lysosome. In this study, a synthetic glycan terminated with mannose-6-phosphate residues was attached to beta-cyclodextrin and its effect on cellular internalization and transport to the lysosome was investigated.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Editorial Material
Chemistry, Organic
Matthieu Sollogoub, Emmanuelle Schulz
Summary: The Division de Chimie Organique (DCO) of the Societe Chimique de France (SCF) and the European Journal of Organic Chemistry are collaborating for the second year in a row to honor the recipients of the 2021 DCO Awards.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Hugo Madec, Francisca Figueiredo, Kevin Cariou, Sylvain Roland, Matthieu Sollogoub, Gilles Gasser
Summary: The development of organometallic catalysis has expanded the toolbox of synthetic chemists and paved the way for bio-compatible reactions in water. Performing metal-catalysed reactions within living cells or organisms poses additional constraints, requiring metal complexes with good efficiency, low concentration, cell specificity, cellular uptake, and low toxicity.
Article
Chemistry, Multidisciplinary
Enxu Liu, Sawsen Cherraben, Laora Boulo, Claire Troufflard, Bernold Hasenknopf, Guillaume Vives, Matthieu Sollogoub
Summary: Researchers have developed a novel molecular information ratchet that is sensitive to both the position and orientation of a moving macrocycle. The use of a cone-shaped chiral macrocycle allows for kinetic biases, and the possibility of selective functionalization offers new opportunities in the design of molecular motors.
Article
Chemistry, Physical
Walid Hamza Saadaoui, Cecile Machut, Sebastien Rio, Sandra Bigot, Vincent Wiatz, Eric Monflier, Anne Ponchel
Summary: The direct conversion of glucose to 5-hydroxymethylfurfural was investigated using phosphated niobium oxide-carbon catalysts in a biphasic system. A facile approach for generating Nb-based composites with high metal loadings (around 20%) was developed through hydrothermal carbonization, calcination, and H3PO4 adsorption. Catalysts were characterized through various techniques, and NbP@C-RB30 and NbP@C-RB15 prepared using oligosaccharides and low water volumes exhibited higher efficiency for HMF production.
MOLECULAR CATALYSIS
(2023)
Article
Chemistry, Multidisciplinary
Dmitri Colesnic, Pedro J. Hernando, Lise-Marie Chamoreau, Laurent Bouteiller, Mickael Menand, Matthieu Sollogoub
Summary: Regioselective di-functionalization of a cyclodextrin enables controlled orientation of hydrophobic domains, leading to a unique hierarchical assembly in the solid state. This assembly involves synergistic host-guest inclusions, directed hydrophobic effect, and hydrogen bonding, which together create a porous organic architecture.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Applied
Abdelghani El Mouat, Taha El Assimi, Mustapha Raihane, Jeremy Ternel, Herve Beicout, Eric Monflier, Sebastien Tilloy, Mohammed Lahcini
Summary: In this study, hyperbranched poly(epsilon-caprolactones) were synthesized and used as coating materials for slow-release DAP fertilizer. The prepared polymers (SFO-O-g-PCL) were confirmed by NMR and FTIR analysis. The coated DAP fertilizer granules showed a significant decrease in the release of P2O5 compared to the uncoated DAP fertilizer. This research opens up possibilities for the production of biodegradable coating agents using hydrophobic polyesters and bio-based oils.
PROGRESS IN ORGANIC COATINGS
(2023)
Editorial Material
Multidisciplinary Sciences
Anne Ponchel, Eric Monflier
Summary: This article comments on a recent study on the selective recovery of gold through a hierarchical host-guest assembly specifically built from beta-CD.
NATURE COMMUNICATIONS
(2023)
Article
Engineering, Environmental
Dario Lacalamita, Guillaume Hoyez, Chiara Mongiovi, Anne Ponchel, Nadia Morin-Crini, Cyril Rousseau, Christophe Loup, Jolanta Rousseau, Marina Raschetti, Eric Monflier, Vincent Placet, Gregorio Crini
Summary: In recent years, there have been numerous studies on the use of metal organic frameworks (MOFs) to remove contaminants from aqueous solutions. However, little is known about using MOFs as adsorbents for the removal of fluoride ions from real effluents. In this study, a highly porous MOF, UiO-66-NH2, was used for the final treatment of complex discharge waters containing fluoride ions. The batch experiments showed that the MOF exhibited high adsorption capacities for fluoride ions, effectively reducing their concentrations in the effluent.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Thomas Roth, Rebecca Evertz, Niklas Kopplin, Sebastien Tilloy, Eric Monflier, Dieter Vogt, Thomas Seidensticker
Summary: Aqueous hydroaminomethylation (HAM) is a Green process for the efficient production of amines from basic chemicals. In this study, a continuous process for HAM in an aqueous multiphase system was successfully established. By adding randomly methylated-beta-cyclodextrin as a mass transfer agent, high yields and selectivities were achieved in several continuous experiments. The addition of cyclodextrin made it unnecessary to use solvents.
Article
Chemistry, Multidisciplinary
Chryslain Becquet, Michel Ferreira, Herve Bricout, Baptiste Quienne, Sylvain Caillol, Eric Monflier, Sebastien Tilloy
Summary: Jojoba oil ester was functionalized with alcohol groups via hydrohydroxymethylation catalyzed by a Rh/amine system. Under optimized conditions, a full conversion and a 99% yield of alcohol products were achieved. The catalytic system could be recycled at least 10 times without significant loss of activity. The hydrohydroxymethylated products were successfully used as monomers for the synthesis of a new biobased polyurethane with good thermal and mechanical properties.
Article
Polymer Science
Cedric Decarpigny, Anne Ponchel, Eric Monflier, Rudina Bleta
Summary: Surface modification is crucial for the production of highly efficient and stable enzymatic nanoreactors. This study investigates the impact of various functional groups on the catalytic performance of lipase B from Candida antarctica (CALB) in a supramolecular hydrogel. Results show that different functional groups have different effects on the catalytic activity and stability of CALB. Additionally, the use of cationic cross-linked beta-CD as an enzyme-stabilizing agent enhances the operational stability of the biocatalyst. These findings suggest that the supramolecular silicified hydrogel monoliths with hierarchical porosity have potential applications in biocatalytic continuous flow processes.
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)
