Journal
NEW JOURNAL OF CHEMISTRY
Volume 32, Issue 2, Pages 197-200Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b716283a
Keywords
-
Categories
Ask authors/readers for more resources
The X-ray structure determination of [L2Cu2Gd2(NO3)(6)(H2O)(2)]-(0.5H(2)O) (L = bis-[(2-hydroxy-3-ethoxyphenyl) methylene]4,4'- methylenedianiline) confirms the existence of a tetranuclear double-stranded homotopic and unsaturated helicate. In each Cu - Gd pair, the reduced Cu center dot center dot center dot Gd distance allows ferromagnetic Cu - Gd superexchange interactions through two phenoxo oxygen atoms. Replacement of gadolinium ions by terbium ions yields the first example of a helicate behaving as a single molecule magnet (SMM).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available