4.6 Article

Microstructural characterization of gold nanoparticles synthesized by solution plasma processing

Journal

NANOTECHNOLOGY
Volume 22, Issue 45, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/22/45/455701

Keywords

-

Funding

  1. CREST-JST
  2. Knowledge Cluster Initiative Tokai Region Nanotechnology Manufacturing Cluster
  3. Grants-in-Aid for Scientific Research [22656165] Funding Source: KAKEN

Ask authors/readers for more resources

Microstructural characteristics of gold nanoparticles (Au NPs) fabricated by solution plasma processing (SPP) in reverse micelle solutions have been studied by high-resolution transmission electron microscopy (HRTEM). The synthesized Au NPs, with an average size of 6.3 +/- 1.4 nm, have different crystal characteristics; fcc single-crystalline particles, multiply twinned particles (MTPs), and incomplete MTPs (single-nanotwinned fcc configuration). The crystal structure characteristics of the Au NPs synthesized by the SPP method were analyzed and compared with similar-size Au NPs obtained by the conventional chemical reduction synthesis (CRS) method. The TEM analysis results show that the Au NPs synthesized by the CRS method have shapes and crystal structures similar to those nanoparticles obtained by the SPP method. However, from the detailed HRTEM analysis, the relative number of the Au MTPs and incomplete MTPs to the total number of the Au NPs synthesized by the SPP method was observed to be around 94%, whereas the relative number of these kinds of crystal structures fabricated by the CRS method was about 63%. It is most likely that the enhanced formation of the Au MTPs is due to the fact that the SPP method generates highly reaction-activated species under low environmental temperature conditions.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Nanoscience & Nanotechnology

Natural Self-Confined Structure Effectively Suppressing Volume Expansion toward Advanced Lithium Storage

Yun Zhang, Jun Huang, Zhu Liao, Anyi Hu, Xinyu Li, Nagahiro Saito, Zhengxi Zhang, Li Yang, Shin-ichi Hirano

Summary: By optimizing the crystal structure, the layered compound L0.9NMO not only achieves high initial Coulombic efficiency and stable cycling reversibility, but also effectively suppresses volume expansion and enhances conductivity.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Facile In Situ Synthesis of Amphiphilic Carbon-Supported Pt: Innovative Catalyst Preparation for Proton Exchange Membrane Fuel Cells

Mongkol Tipplook, Gasidit Panomsuwan, Yukihiro Muta, Nagahiro Saito

Summary: A study demonstrated a one-step synthesis of amphiphilic functional group-modified carbon-supported platinum catalyst via liquid-phase plasma process, improving the efficiency and durability of PEMFCs. The research findings suggest that the number of hydrophilic and hydrophobic characters on the carbon surface plays a crucial role in the performance of PEMFCs.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Au nanoparticle-decorated TiO2 hollow fibers with enhanced visible-light photocatalytic activity toward dye degradation

Gasidit Panomsuwan, Sittan Wongcharoen, Chayanapat Chokradcharoen, Mongkol Tipplook, Oratai Jongprateep, Nagahiro Saito

Summary: TiO2 hollow fibers decorated with Au nanoparticles show enhanced photocatalytic activity for methylene blue degradation under visible light, attributed to the combination of effective light-harvesting by the hollow structure and efficient visible-light absorption and charge separation induced by Au nanoparticles.

RSC ADVANCES (2021)

Article Chemistry, Physical

Asymmetric Porous and Highly Hydrophilic Sulfonated Cellulose/Biomembrane Functioning as a Separator in a Lithium-Ion Battery

Satita Thiangtham, Nagahiro Saito, Hathaikarn Manuspiya

Summary: The study demonstrated that incorporating sulfonated cellulose as a biofiller in biomembranes can significantly enhance the porosity and ionic conductivity of the separators, thereby improving the performance of lithium-ion batteries.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Graphitic N-doped graphene via solution plasma with a single dielectric barrier

Jiangqi Niu, Chayanaphat Chokradjaroen, Nagahiro Saito

Summary: Graphitic nitrogen-doped graphene with high nitrogen content was successfully synthesized using a solution plasma method. The proposed method reduces excessive current, stabilizes the glow plasma, and promotes the preservation of nitrogen atoms and the formation of a graphitic carbon framework.

CARBON (2022)

Article Materials Science, Multidisciplinary

Nanoscale advanced carbons as an anode for lithium-ion battery

Rinyarat Naraprawatphong, Chayanaphat Chokradjaroen, Satita Thiangtham, Li Yang, Nagahiro Saito

Summary: This review discusses the structures, main properties, and synthesis methods of nanoscale advanced carbons, and summarizes currently good candidates for anode material for lithium-ion batteries. The importance of the primary function and the synergistic effect of nanoscale advanced carbons with active electrode species is emphasized. This review provides a promising tool for selecting anode electrode materials and designing the next generation of advanced lithium-ion batteries.

MATERIALS TODAY ADVANCES (2022)

Article Chemistry, Physical

Morphological Evolution of Gold Nanoparticles Synthesized via Solution Plasma Sputtering: Effect of Sodium Chloride Concentration and Storage Time

Jidapa Chantaramethakul, Nicha Choophun, Chayanaphat Chokradjaroen, Anyarat Watthanaphanit, Nagahiro Saito, Gasidit Panomsuwan

Summary: Morphological control of gold nanoparticles (AuNPs) synthesized via solution plasma sputtering (SPS) in sodium chloride (NaCl) solutions has been investigated. The size, distribution, and stability of AuNPs were examined over 30 days of storage. The results show that the NaCl concentration and storage time critically influence the morphological evolution and stability of AuNPs. High NaCl concentration leads to coalescence and sedimentation of AuNPs. Additionally, oxidative etching affects the size and distribution of AuNPs, with larger particles observed at higher NaCl concentrations.

JOURNAL OF PHYSICAL CHEMISTRY C (2023)

Article Chemistry, Physical

Correlation function of specific capacity and electrical conductivity on carbon materials by multivariate analysis

Junmo Moon, Hojung Yun, Junzo Ukai, Chayanaphat Chokradjaroen, Satita Thiangtham, Takeshi Hashimoto, Kyusung Kim, Yasuyuki Sawada, Nagahiro Saito

Summary: This study investigates the factors affecting the specific capacity and electrical conductivity of carbon materials used in Li-ion batteries for electric vehicles. Correlation analysis and descriptor vectors were used to examine the intercalation of Li ions and the number of graphene layers on the surface, which were found to have significant impacts on the capacity and conductivity. The study proposes correlation equations based on these findings and validates their effectiveness using experimental data and statistical methods. A candidate structure for improving battery performance is also proposed.

CARBON (2023)

Article Materials Science, Multidisciplinary

Preparation of lightweight, high hardness multi-component systems induced by partial oxidation and hard intermetallic phase formation

Seulgee Lee, Chayanaphat Chokradjaroen, Yasuyuki Sawada, Nagahiro Saito

Summary: Ternary and quaternary composites of Mg-Al-Ti and Mg-Al-Ti-Cu systems were successfully prepared using mechanical alloying and spark plasma sintering. The optimized process resulted in uniform composite microstructure, and the addition of Cu significantly improved the hardness.

JOURNAL OF MATERIALS RESEARCH (2023)

Article Chemistry, Multidisciplinary

Introducing micropores into carbon nanoparticles synthesized via a solution plasma process by thermal treatment and their charge storage properties in supercapacitors

Myo Myo Thu, Nattapat Chaiammart, Oratai Jongprateep, Ratchatee Techapiesancharoenkij, Aye Aye Thant, Nagahiro Saito, Gasidit Panomsuwan

Summary: Carbon nanoparticles synthesized via solution plasma process were thermally treated at different temperatures to introduce micropores and adjust pore structures for supercapacitor applications. The treatment temperature significantly affected the specific surface area and oxygen content of the nanoparticles. The charge storage properties were evaluated, and the nanoparticles treated at high temperatures showed improved cycling stability.

RSC ADVANCES (2023)

Article Chemistry, Multidisciplinary

Facile synthesis of ZnO nanobullets by solution plasma without chemical additives

Kyusung Kim, Sangwoo Chae, Pil Gyu Choi, Toshio Itoh, Nagahiro Saito, Yoshitake Masuda

Summary: ZnO nano-bullets were synthesized using solution plasma without any chemical agents, exhibiting high crystalline structure with (100) and (101) crystal facets, showing potential for applications in advanced technologies.

RSC ADVANCES (2021)

Article Materials Science, Multidisciplinary

Li-air battery and ORR activity of nanocarbons produced with good synthesis rate by solution plasma process

Md Zahidul Islam, Anyarat Watthanaphanit, Sangwoo Chae, Nagahiro Saito

Summary: Nanocarbons were successfully synthesized using solution plasma process from benzene, nitro-benzene, and aniline, showing potential applications in next-generation batteries and energy conversion devices such as lithium-air batteries. The synthesized nanocarbons exhibited different properties, with the highest synthesis rate for benzene nanocarbon and high special capacity for aniline-derived nanocarbon in lithium-air battery. The oxygen reduction reaction in nanocarbons is crucial for the next-generation batteries and fuel cells.

MATERIALS ADVANCES (2021)

Article Materials Science, Multidisciplinary

N-Doped few-layer graphene encapsulated Pt-based bimetallic nanoparticles via solution plasma as an efficient oxygen catalyst for the oxygen reduction reaction

Phu Quoc Phan, Rinyarat Naraprawatphong, Phuwadej Pornaroontham, Junmu Park, Chayanaphat Chokradjaroen, Nagahiro Saito

Summary: The N-doped few-layer graphene encapsulated Pt-based bimetallic nanoparticles were successfully synthesized via the solution plasma (SP) method. The synthesis strategy exhibited fine core-shell structured nanoparticles with acceptable electrocatalytic activity towards the oxygen reduction reaction (ORR) and excellent durability, possibly attributed to the synergistic effect of the Pt-based bimetallic core and N-doped graphene shell containing high amounts of pyridinic-N and quaternary-N.

MATERIALS ADVANCES (2021)

Article Chemistry, Multidisciplinary

In situsynthesis of copper nanoparticles encapsulated by nitrogen-doped graphene at room temperatureviasolution plasma

Phu Quoc Phan, Sangwoo Chae, Phuwadej Pornaroontham, Yukihiro Muta, Kyusung Kim, Xiaoyang Wang, Nagahiro Saito

RSC ADVANCES (2020)

Article Nanoscience & Nanotechnology

Single-Walled Carbon Nanotubes Wrapped by Cationic Nitrogen-Doped Carbon for Electrocatalytic Applications

Sangwoo Chae, Phu Quoc Phan, Gasidit Panomsuwan, Maria Antoaneta Bratescu, Takeshi Hashimoto, Katsuya Teshima, Nagahiro Saito

ACS APPLIED NANO MATERIALS (2020)

No Data Available