4.7 Article

Utilization of NaCl solutions to clean ultrafiltration membranes fouled by whey protein concentrates

Journal

SEPARATION AND PURIFICATION TECHNOLOGY
Volume 150, Issue -, Pages 95-101

Publisher

ELSEVIER
DOI: 10.1016/j.seppur.2015.06.039

Keywords

Ultrafiltration; Membrane cleaning; Whey protein concentrate; NaCl solutions

Funding

  1. Spanish Ministry of Science and Innovation [CTM2010-20186]

Ask authors/readers for more resources

In this work, whey protein concentrate (WPC) solutions at different concentrations (22.2, 333 and 150 g L-1) were used to foul three ultrafiltration (UF) membranes of different materials and molecular weight cut-offs (MWCOs): a polyethersulfone (PES) membrane of 5 kDa, a ceramic ZrO2-TiO2 membrane of 15 kDa and a permanently hydrophilic polyethersulfone (PESH) membrane of 30 kDa. NaCl solutions at different salt concentrations, temperatures and crossflow velocities were used to clean the UF membranes tested. The cleaning efficiency was related to the MWCO, membrane material and operating conditions during fouling and cleaning steps. NaCl solutions were able to completely clean the membranes fouled with the WPC solutions at the lowest concentration tested. As WPC concentration increased, the hydraulic cleaning efficiency (HCE) decreased. The results demonstrated that an increase in temperature and crossflow velocity of the cleaning solution caused an increase in the HCE. Regarding NaCl concentration, the HCE increased up to an optimal value. As the concentration was greater than this value, the cleaning efficiency decreased. In addition, an equation that correlates the cleaning efficiency to the operating parameters studied in this work (temperature, NaCl concentration, crossflow velocity in the cleaning procedure and WPC concentration during the fouling step) was developed and then, an optimization analysis was performed to determine the values of the parameters that lead to a 100% cleaning efficiency. (C) 2015 Published by Elsevier B.V.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Chemical

NaCl precleaning of microfiltration membranes fouled with oil-in-water emulsions: Impact on fouling dislodgment

C. Rouquie, A. Szymczyk, M. Rabiller-Baudry, H. Roberge, P. Abellan, A. Riaublanc, M. Frappart, S. Alvarez-Blanco, E. Couallier

Summary: Although membrane filtration for biorefining of microalgae has gained increasing interest, little research has been done on membrane regeneration after fouling by vegetable products. In this study, the use of NaCl solution for precleaning of membranes fouled by microalgae lipid emulsion was investigated. The results showed that NaCl can significantly reduce internal fouling and facilitate subsequent cleaning steps. This work contributes to the development of cost-effective and environmentally friendly cleaning procedures for separation processes in microalgae biorefinery.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Food Science & Technology

Exploring the extraction of the bioactive content from the two-phase olive mill waste and further purification by ultrafiltration

Carmen M. Sanchez-Arevalo, Alicia Iborra-Clar, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: This study focused on the solid-liquid extraction of bioactive compounds from two-phase olive mill waste using ultrasound-assisted extraction. The optimal experimental conditions resulted in a recovery of over 6.8 mg/g of bioactive content, which was later purified by ultrafiltration. The research not only added value to the waste, but also reduced its organic load and phytotoxicity, thus protecting the ecosystem of the disposal area.

LWT-FOOD SCIENCE AND TECHNOLOGY (2022)

Article Engineering, Chemical

Recovery of phenolic compounds from olive oil washing wastewater by adsorption/desorption process

Magdalena Cifuentes-Cabezas, Carmen Maria Sanchez-Arevalo, Jose Antonio Mendoza- Roca, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: An adsorption/desorption process using Purolite non-ionic resins was investigated to recover phenolic compounds from agroindustry wastewater. The optimal resin concentration and desorption solvent for maximum recovery were determined, and the adsorption mechanisms were characterized using kinetic and isotherm models. The MN200 resin was found to be the most effective adsorbent, achieving a 91% recovery of phenolic compounds.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Engineering, Environmental

Nanofiltration of wastewaters from olive oil production: Study of operating conditions and analysis of fouling by 2D fluorescence and FTIR spectroscopy

Magdalena Cifuentes-Cabezas, Claudia F. Galinha, Joao G. Crespo, Maria Cinta Vincent-Vela, Jose Antonio Mendoza-Roca, Silvia Alvarez-Blanco

Summary: The presented work aims to solve the problem of large volumes of oil mill wastewater and proposes nanofiltration as a possible second stage treatment. Different membranes were tested and it was found that the NF270 membrane under specific conditions showed the best concentration of phenolic compounds with high permeate flux and low fouling. Furthermore, spectroscopic techniques were used to study membrane fouling and effectiveness of cleaning protocols.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Chemical

Feasibility of several commercial membranes to recover valuable phenolic compounds from extracts of wet olive pomace through organic-solvent nanofiltration

Carmen M. Sanchez-Arevalo, Tim Croes, Bart Van der Bruggen, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: Organic-solvent nanofiltration (OSN) has been used to purify and fractionate phenolic compounds in wet olive pomace. Nine commercial OSN membranes were tested, and DuraMem (R) 500, NFX, and NF270 membranes showed satisfactory permeate flux values. Contact angle measurements and AFM analysis provided insight into the interaction between the ethanol/water solution and the membranes. Liquid chromatography coupled to mass spectrometry and/or refractive index detector confirmed low rejection of the target phenolic compounds (less than 10% for hydroxytyrosol) and high rejection of undesired compounds.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Environmental

Management of reject streams from hybrid membrane processes applied to phenolic compounds removal from olive mill wastewater by adsorption/desorption and biological processes

Magdalena Cifuentes-Cabezas, Jose Antonio Mendoza-Roca, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: This study focuses on the valorization of concentrates obtained from membrane processes for the purification of olive oil washing wastewater. The combination of adsorption/desorption process and biological treatment successfully recovered phenolic compounds and eliminated organic matter, providing a solution for circular economy in olive oil processing wastewater treatment.

JOURNAL OF WATER PROCESS ENGINEERING (2022)

Article Biochemistry & Molecular Biology

Combining Ultrafiltration and Nanofiltration to Obtain a Concentrated Extract of Purified Polyphenols from Wet Olive Pomace

Carmen M. Sanchez-Arevalo, Ane Perez Garcia-Serrano, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: Despite concerns about the environmental impact of wet olive pomace, it actually contains valuable phenolic compounds that can be recovered. This study proposes an integrated process involving ultrasound-assisted extraction, followed by filtration. Different commercial membranes were tested, and satisfactory results were obtained with the UP005 membrane, which provided efficient purification and high permeate flux. Finally, a nanofiltration process using the NF270 membrane achieved the concentration of the purified polyphenols.

MEMBRANES (2023)

Article Food Science & Technology

Deep Study on Fouling Modelling of Ultrafiltration Membranes Used for OMW Treatment: Comparison Between Semi-empirical Models, Response Surface, and Artificial Neural Networks

Magdalena Cifuentes-Cabezas, Jose Luis Bohorquez-Zurita, Sandra Gil-Herrero, Maria Cinta Vincent-Vela, Jose Antonio Mendoza-Roca, Silvia Alvarez-Blanco

Summary: This study focused on the effect of transmembrane pressure and cross flow velocity on the permeate flux of different ultrafiltration membranes for the treatment of olive mill wastewater. Semi-empirical models, statistical methods, and machine learning techniques were used. The series resistance model and combined model accurately represented the experimental data, indicating the contributions of cake layer formation and pore blockage to membrane fouling. Inorganic membranes showed a higher tendency for irreversible fouling. Response surface methodology and artificial neural networks were effective in analyzing the significant variables and their impacts. The study provides a better understanding of the data modeling of different ultrafiltration membranes for olive mill wastewater treatment.

FOOD AND BIOPROCESS TECHNOLOGY (2023)

Article Biotechnology & Applied Microbiology

Concentration of phenolic compounds from olive washing wastewater by forward osmosis using table olive fermentation brine as draw solution

Magdalena Cifuentes-Cabezas, Alessio Pavani, Maria Cinta Vincent-Vela, Jose Antonio Mendoza-Roca, Silvia Alvarez-Blanco

Summary: The olive industry generates a large volume of oil mill wastewater (OMW) and table olive wastewater (TOW), which have high concentrations of organic matter, phenolic compounds, and conductivity. Proper management of these wastewaters is crucial due to their toxic impacts on the environment. Forward osmosis (FO) process was tested to concentrate phenolic compounds for recovery, and two membranes (OsmoF2OTM and HFFO.6) were evaluated. Both membranes demonstrated effective concentration of phenolic compounds with acceptable volume reduction. FO shows promise for concentrating phenolic compounds from OOWW and diluting FTOP simultaneously.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2023)

Article Food Science & Technology

Solvent-resistant ultrafiltration to recover bioactive compounds from wet olive pomace extracts

Carmen M. Sanchez-Arevalo, Alicia Iborra-Clar, Maria Cinta Vincent-Vela, Silvia Alvarez-Blanco

Summary: Wet olive pomace can be used as a valuable source of phenolic compounds, which can be efficiently extracted using ethanol/water. Different ultrafiltration membranes were tested to purify the phenolic compounds in the extracts, and UF010104 membrane showed the highest permeate flux and rejection of organic matter, achieving the purification of the phenolic compounds in the permeate stream.

LWT-FOOD SCIENCE AND TECHNOLOGY (2023)

Article Biochemistry & Molecular Biology

Theoretical Model for the Prediction of Water Flux during the Concentration of an Olive Mill Wastewater Model Solution by Means of Forward Osmosis

Magdalena Cifuentes-Cabezas, Silvia Alvarez-Blanco, Jose Antonio Mendoza-Roca, Maria Cinta Vincent-Vela, Jose M. Gozalvez-Zafrilla

Summary: Understanding the dynamics of agent interaction is crucial for the operation and design of industrial wastewater management processes. This study developed a theoretical model to predict water flux in two different membranes using a sodium chloride solution as the draw solution. The model considered the contribution of organic compounds to osmotic pressure, as well as the membrane characteristics and module geometry. The results showed variations in flux prediction based on the membrane type, feed solution, and draw solution, with a greater influence of phenolic compounds observed in the cellulose triacetate membrane.

MEMBRANES (2023)

Article Biotechnology & Applied Microbiology

Use of ultrafiltration ceramic membranes as a first step treatment for olive oil washing wastewater

Magdalena Cifuentes-Cabezas, Maria Cinta Vincent-Velaa, Jose Antonio Mendoza-Roca, Silvia Alvarez-Blanco

Summary: Olive oil production generates wastewater containing phenolic compounds with antioxidant characteristics. Ultrafiltration treatment effectively removes color, turbidity, and organic pollutants from the wastewater, while having little impact on the recovery of phenolic compounds.

FOOD AND BIOPRODUCTS PROCESSING (2022)

Article Engineering, Chemical

A tough double-network ion gel membrane based on poly (ionic liquid) for efficient carbon capture

Yunfei Yu, Xue Yang, Chenchen Zhang, Jie Chen, Wei Lin, Jianqiang Meng

Summary: This study reports an environmentally friendly and simple approach for preparing double-network (DN) ion gel membranes with high strength and excellent gas separation performance. By optimizing crosslinking density, mass ratio, and the type and content of free ionic liquid, the mechanical and gas separation properties of the DN membrane are improved.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

An innovative dual-strengthening pretreatment to improve Li and Co leaching in spent lithium-ion batteries: Pyrolysis combined with mechanical grinding

Si-qi Jiang, Qiang Gao, Xi-guang Li, Chao-zhu Deng, Jun Qiu, Xiang-nan Zhu

Summary: A dual-strengthening pretreatment method is proposed to remove PVDF more efficiently and enhance the leaching of LiCoO2. Experimental results show that dual-strengthening pretreatment can effectively remove PVDF and significantly improve the leaching efficiency compared to single pretreatment methods.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Rapid fabrication of composite membranes based on conjugated microporous polymers: Microstructural design for performance optimization

Zengchi Hu, Xiaoyu Wang, Xiaohui Zhang, Xue Li, Jiangbin Xia

Summary: The rapid fabrication of high-performance composite membranes based on CMPs using simple and low-cost methods is challenging. In this study, three CMPs-based composite membranes were rapidly fabricated with adjustable size using unidirectional diffusion synthesis. The microstructural design enhanced the rejection rates of the membranes and they showed strong hydrolytic resistance, thermal stability, and acid-base resistance. Electrostatic adsorption and the adjustable microstructures significantly varied the repellence of the membranes to different charged molecules.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Dual nature brilliant adsorbent engineering by converting an Al-based MOF to defect rich quasi-MOF

Farzaneh Rouhani, Matineh Ayedi, Nasser Safari

Summary: Introducing defects into porous metal-organic frameworks is important for improving their adsorption performance. Quasi-MOFs, an underutilized variant of large-scale, fundamentally deficient MOFs, have been found to have substantial amounts of unsaturated metal sites to offset the drawbacks of MOFs. In this study, a quasi-MOF was produced using a water-stable MOF and demonstrated significantly improved phosphate adsorption capability due to the presence of defect sites.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Liquid-liquid extraction of sinapic acid from a mustard seed by-product using a hollow fiber membrane contactor

Valentin Reungoat, Morad Chadni, Louis M. M. Mouterde, Fanny Brunissen, Florent Allais, Helene Ducatel, Irina Ioannou

Summary: This study focuses on the recovery of sinapic acid using liquid-liquid extraction assisted by a hollow fiber membrane contactor from an aqueous feed obtained through the hydrolysis of mustard bran. The screening of solvents of different chemical nature showed that all tested solvents had an extraction efficiency of more than 80% for pH < 5. Four solvents were selected for use in the hollow fiber membrane contactor, and the volatile solvents showed higher mass transfer coefficients compared to non-volatile solvents. The extraction efficiency was intensified by increasing the initial concentration of sinapic acid and the feed-to-solvent ratio. CPME was found to have optimal recovery efficiency at a phase ratio of 8:1, yielding 0.9 g of sinapic acid per liter of CPME used.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Hydrophobic deep eutectic solvents for the direct leaching of nickel laterite ores: Selectivity and reusability investigations

Takahiro Sakamoto, Takafumi Hanada, Hayate Sato, Mayu Kamisono, Masahiro Goto

Summary: The emergence of the battery society has led to a high demand for battery metals, resulting in a strain on their supply. This study introduces a novel technique using a hydrophobic deep eutectic solvent (DES) for leaching and recovering battery metals from low-grade nickel laterite ores. The DES enables selective leaching and recovery of the metals, offering a promising pathway for the extraction of critical battery metals.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Quantification of overcompensated cations in layer-by-layer membrane by Orange yellow II

Rongrong He, Jiarui Chen, Chunyao Zhang, Dan Lu, Lin Zhang, Tao He

Summary: Researcher has developed a method to quantify the charge density in nanofiltration (NF) membrane separation layer and applied it in NF membranes that can separate Mg2+ and Li+. The results showed that overcompensated amine groups played a major role, and there was a linear relationship between charge density and coating bi-layers or PAH layers.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Insight of multifunctional Cu-alginate hydrogel membrane for precise molecule/ion separation applications

Zhijian Zhang, Min Chen, Zhe Lin, Zhichao Yang, Yafeng Du, Zhihui Chen, Zhenhao Yang, Kongyin Zhao, Ligang Lin

Summary: Membrane technology plays an important role in molecular/ion separation processes, but faces challenges such as membrane fouling. This study introduces a new ion-crosslinking method to fabricate copper alginate hydrogel membranes with improved mechanical strength and antimicrobial capabilities. The membranes exhibit excellent separation performance and enhanced long-term molecule/ion separation through improved anti-swelling properties. Molecular dynamics simulations and life cycle analysis highlight the pore structure and environmental friendliness of the hydrogel membranes. These findings provide valuable insights for developing sustainable hydrogel membranes with stable performance and high separation efficiency.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Activation of persulfate by magnetic Mg/Mn-layered double oxide-doped biochar composite for ciprofloxacin removal and bacterial inactivation

Dongmei Liu, Aiying Guo, Yanling Qi, Zhixin Ji, Hongjuan Li, Zhiwei Zhang, Xinyue Zhang, Kunze Wu, Aijun Cai

Summary: In this study, a stable magnetic Mg/Mn-layered double oxide-doped biochar composite (MgMnLDO-MBC) was prepared and successfully used for the removal of antibiotics and bacteria from wastewater. The composite exhibited enhanced surface areas, adsorption sites, and free radicals, leading to improved catalytic activity. The effects of different factors on the removal efficiency were evaluated, and the composite showed good reusability.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Rapid peroxymonosulfate activation by self-assembly of layered fluorine-free MXene with nanofibrous Co3O4: Antibiotic degradation and electron transfer mechanism

Feng Wang, Zhaoyong Bian, Yaru Zhang, Wenchao Yu, Qiang Zhang, Hui Wang

Summary: In this study, a nanofibrous layered structure of Ff-Ti3C2Tx-Co3O4 was prepared by self-assembling nanofibrous Co3O4 with lamellar fluorine-free MXene (Ff-Ti3C2Tx). The Ff-Ti3C2Tx-Co3O4 exhibited excellent catalytic activity for degradation, resistant to ionic interference, and maintained high removal efficiency of sulfamethoxazole (SMX) in municipal wastewater. The rapid SMX degradation involved fast electron transfer in redox cycles with PMS and the generation of 1O2 via PMS ->center dot O2  -> 1O2. This work provides new insights into antibiotic degradation mechanisms and electron transfer based on PMS activation.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Differently charged polyacrylamides (PAMs) significantly affect adsorption affinity and associated floc growth behaviors during ballasted flocculation: Performance and mechanism

Weipeng He, Jiacheng Luo, Yujie Wu, Tianhao Luo, Chen Tang

Summary: This study comparatively evaluated the role of cationic, anionic, and nonionic polyacrylamides (PAMs) in ballasted flocculation of clay suspensions under different aluminum sulfate (AS) coagulant dosages. The selection of PAMs and AS dosage had a significant influence on the size and shear resistance of ballasted floc aggregates.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Polymeric membrane with nanohybrids of Cu nanocomposites and metalloporphyrin-based nanosheets for enzyme-like catalytic degradation of Congo Red

Lixian Wang, Lizhi Zhao, Didi Si, Zhixin Li, Huiqin An, Hui Ye, Qingping Xin, Hong Li, Yuzhong Zhang

Summary: Metalloporphyrin-based nanozymes integrated with poly (vinylidene fluoride) membrane show high catalytic activity and reusability for the decolorization of Congo Red dye in continuous flow process.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Facile synthesis of ball milling and magnetization co-modified sludge-derived biochar for efficient adsorbing environmental concentration sulfamethoxazole from various waters: Performance and mechanism

Yongfei Ma, Chenyu Zeng, Yongzhen Ding, Jiayi Tang, Ondrej Masek, Zhikang Deng, Rui Mu, Zulin Zhang

Summary: In this study, sludge-derived biochar (SBC) was functionalized with various iron salts to enhance its adsorption ability for sulfamethoxazole (SMX) and magnetic collection performance. Ball milling was further employed to treat the optimal iron salt functionalized SBC (MSBC), resulting in ball milled SBC (BMSBC) with improved adsorption performance for SMX. The dominant driving mechanism for SMX adsorption onto BMSBC was confirmed to be multiple physicochemical forces, including 7C-7C conjugation, pore filling, H-bonding, Fe-O complexation, and electrostatic interactions. BMSBC exhibited favorable adsorption ability for SMX in actual waters and could be easily collected within 1 min due to its magnetic sensitivity.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Facile fabrication of non-fluorine polymer brush/loop surfaces for oil/water separation and self-cleaning applications

Jinglin Tan, Xiaohui Mao, Wenjihao Hu, Hongbo Zeng

Summary: This study investigates the influence of PDMS chain architectures on surface properties and reveals that PDMS coatings with looped structures exhibit superior hydrophobicity, self-cleaning, and water sliding compared to coatings with linear structures. Additionally, both looped and linear PDMS coated stainless steel mesh/polyester fibers show efficient separation of oil/water mixture.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Fabrication of sandwich-structured capacitor containing core@shell polystyrene@graphene oxide microspheres for switchable removal of dyes from water by dielectrophoresis force

Wei-Liang Chen, Chih-Chia Cheng, Chien-Hsing Lu, Jem-Kun Chen

Summary: This study designs a novel sandwich-structured capacitor that reduces the absorption time of pollutants using dielectrophoresis force. By coating graphene oxide on polystyrene microspheres as adsorbents and encapsulating them within the capacitor, the adsorption rate is significantly enhanced. Additionally, frequency manipulation allows for the recycling of adsorbents and concentration of dyes, minimizing secondary pollution.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)