Journal
NANOSCALE
Volume 10, Issue 3, Pages 914-920Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr07097g
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Funding
- German Science Foundation (DFG)
- Interdisciplinary Center for Molecular Materials (ICMM)
- Solar Technologies go Hybrid (SolTech)
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We present a novel, self-assembled nanostructure with selective photocatalytic activity formed from anionic polyoxometalate clusters and cationic dendrimers by electrostatic self-assembly. The association of the components in aqueous solution is driven by ionic interaction and steric factors yielding stable aggregates of a defined size with a coil-like structure. The assemblies show high potential for the application in solar-energy conversion systems due to their enhanced and substrate specific photocatalytic activity.
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